园林废弃物水热炭燃料特性研究

doi:10.19912/j.0254-0096.tynxb.2020-1183

太阳能学报 ›› 2022, Vol. 43 ›› Issue (7): 439-444.DOI: 10.19912/j.0254-0096.tynxb.2020-1183

园林废弃物水热炭燃料特性研究

刘云云¹, 曹运齐¹, 余强², 陈小燕², 王忠铭², 袁振宏²

1.陕西科技大学机电工程学院,西安 710021;
2.中国科学院广州能源研究所,中国科学院可再生能源重点实验室,广东省新能源和可再生能源研究开发与应用重点实验室,广州 510640

收稿日期:2020-11-03 出版日期:2022-07-28 发布日期:2023-01-28
通讯作者: 余强（1983—）,男,博士、研究员,主要从事生物质能方面的研究。yuqiang@ms.giec.ac.cn
基金资助:
国家自然科学基金（51876206）; 广东省自然科学基金（2018A030313012）; 亚热带农业生物资源保护与利用国家重点实验室开放基金（SKLCUSA-b201802）; 中国科学院可再生能源重点实验室开放基金（Y907k51001）

RESEARCH ON FUEL PROPERTIES OF GARDEN WASTE HYDROCHARS

Liu Yunyun¹, Cao Yunqi¹, Yu Qiang², Chen Xiaoyan², Wang Zhongming², Yuan Zhenhong²

1. College of Mechanical and Electrical Engineering, Shaanxi University of Science & Technology, Xi’an 710021, China;
2. Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development, Guangzhou 510640, China

Received:2020-11-03 Online:2022-07-28 Published:2023-01-28

摘要/Abstract

摘要： 以园林废弃物为原料进行水热碳化制备固体生物燃料水热炭,研究不同温度、时间对水热炭燃料特性和燃烧行为的影响,利用燃烧动力学对水热炭燃烧过程及参数进行模拟计算。结果表明：制备的园林废弃物水热炭的燃料特性得到明显改善,且水热炭燃料特性受温度影响较为显著。水热炭热值范围为19.86~27.93 MJ/kg,达到与工业煤相当的水平。水热炭燃烧参数点火温度（Ti）、燃尽温度（Tf）和最大失重率温度（Tm）随碳化温度的升高和时间的增加而增加,其失重量-失重速率（TG-DTG）曲线移向高温区,表明水热炭的热稳定性提高。水热炭燃烧反应过程的动力学拟合符合一级燃烧动力学线性模型（R2=0.93~0.99）,且水热炭具有较高的反应活化能（17.33~41.34 kJ/mol）。

关键词: 生物质能, 园林废弃物, 水热碳化, 水热炭, 燃料特性

Abstract: Hydrochars derived from garden waste were prepared by hydrothermal carbonization （HTC） for solid biofuel production. The effects of temperature and time on the fuel properties and combustion behaviors of hydrochars were investigated, and the combustion process and parameters of hydrochars were also simulated and drived through combustion kinetics analysis. The results showed that the fuel properties of obtained hydrochars were dramatically improved by preparing conditions modification, among which temperature played a critical role on fuel properties improvement. The high heating value of hydrochars was found to be ranging from 19.86 to 27.93 MJ/kg, which reached a level comparable to that of industrial coal. With the increase of HTC temperature and the extension of the time, the combustion values of parameters Ti, Tf and Tm of hydrochars increased, meanwhile, the TG-DTG curves shifted towards the high temperature range, indicating that the thermal stability of the produced hydrochars were enhanced. The results of hydrochar combustion kinetics analysis showed that the combustion reaction process of hydrochars fitted well to the first-order combustion kinetics （R²=0.93-0.99）, and the produced hydrochars had high reaction activation energy （17.33-41.34 kJ/mol）.

Key words: biomass energy, garden waste, hydrothermal carbonization, hydrochar, fuel properties

中图分类号:

TK62
TK69

刘云云, 曹运齐, 余强, 陈小燕, 王忠铭, 袁振宏. 园林废弃物水热炭燃料特性研究[J]. 太阳能学报, 2022, 43(7): 439-444.

Liu Yunyun, Cao Yunqi, Yu Qiang, Chen Xiaoyan, Wang Zhongming, Yuan Zhenhong. RESEARCH ON FUEL PROPERTIES OF GARDEN WASTE HYDROCHARS[J]. Acta Energiae Solaris Sinica, 2022, 43(7): 439-444.

参考文献

[1] SMITH A M, ROSS A B.The Influence of residence time during hydrothermal carbonisation of miscanthus on bio-coal combustion chemistry[J]. Energies, 2019, 12(3): 523.
[2] 吴艳娇, 李伟, 吴琼, 等. 水热炭的制备、性质及应用[J]. 化学进展, 2016, 189(1): 129-138.
WU Y J, LI W, WU Q, et al.Preparation, properties and applications of hydrochar[J]. Progress in chemistry, 2016, 189(1): 129-138.
[3] NONAKA M, HIRAJIMA T, SASAKI K.Upgrading of low rank coal and woody biomass mixture by hydrothermal treatment[J]. Fuel, 2011, 90(8): 2578-2584.
[4] 宋艳培, 庄修政, 詹昊, 等. 城市污泥/褐煤共水热碳化产物的热化学转化特性及规律研究[J]. 化工学报, 2020, 71(5): 2320-2332.
SONG Y P, ZHUANG X Z, ZHAN H, et al.Investigation on thermochemical conversion characteristics and regularity of co-hydrothermal carbonization solid fuel from sewage sludge and lignite[J]. CIESC journal, 2020, 71(5): 2320-2332.
[5] SHARMA H B, PANIGRAHI S, DUBEY B K.Hydrothermal carbonization of yard waste for solid bio-fuel production: study on combustion kinetic, energy properties, grindability and flowability of hydrochar[J]. Waste management, 2019, 91(10): 8-19.
[6] GHAZIASKAR A, MCRAE G A, MACKINTOSH A, et al.Catalyzed hydrothermal carbonization with process liquid recycling[J]. Energy & fuels, 2019, 33(2): 1167-1174.
[7] HEIDARI M, SALAUDEEN S, DUTTA A, et al.Effects of process water recycling and particle sizes on hydrothermal carbonization of biomass[J]. Energy & fuels, 2018, 32(11): 11576-11586.
[8] SABIO E, ALVAREZ-MURILLO A, ROMAN S, et al.Conversion of tomato-peel waste into solid fuel by hydrothermal carbonization: influence of the processing variables[J]. Waste management, 2016, 47(partA): 122-132.
[9] SHUPING Z, YULONG W, MINGDE Y, et al.Pyrolysis characteristics and kinetics of the marine microalgae Dunaliella tertiolecta using thermogravimetric analyzer[J]. Bioresoure technology, 2010, 101(1): 359-365.
[10] 张学飞, 邢献军, 糜梦星, 等. 厨余垃圾及其水热炭燃烧特性与动力学研究[J]. 太阳能学报, 2020, 41(6): 128-135.
ZHANG X F, XING X J, MI M X, et al.Study on combustion characteristics and kinetics of foodwaste and its hydrochars[J]. Acta energiae solaris sinica, 2020, 41(6): 128-135.
[11] GAO Y, WANG X, WANG J, et al.Effect of residence time on chemical and structural properties of hydrochar obtained by hydrothermal carbonization of water hyacinth[J]. Energy, 2013, 58(3): 76-83.
[12] LEE S M, LEE J W.Optimization of biomass torrefaction conditions by the gain and loss method and regression model analysis[J]. Bioresoure technology, 2014, 172(4): 38-43.
[13] MÄKELÄ M, BENAVENTE V, FULLANA A. Hydrothermal carbonization of lignocellulosic biomass: effect of process conditions on hydrochar properties[J]. Applied energy, 2015, 155(5): 76-84.
[14] LI X, LI M-F, BIAN J, et al.Hydrothermal carbonization of bamboo in an oxalic acid solution: effects of acid concentration and retention time on the characteristics of products[J]. RSC advances, 2015, 94(5): 77147-77153.
[15] NIZAMUDDIN S, BALOCH H A, GRIFFIN G J, et al.An overview of effect of process parameters on hydrothermal carbonization of biomass[J]. Renewable and sustainable energy reviews, 2017, 73(12): 89-99.
[16] 宋艳培, 庄修政, 詹昊, 等. 污泥与褐煤共水热碳化的协同特性研究[J]. 化工学报, 2019, 70(8): 3132-3141.
SONG Y P, ZHUANG X Z, ZHAN H, et al.Investigation on synergistic characteristics of sludge and lignite during co-hydrothermal carbonization[J]. CIESC journal, 2020, 70(8): 3132-3141.
[17] LIU Z, QUEK A, KENT H S, et al.Production of solid biochar fuel from waste biomass by hydrothermal carbonization[J]. Fuel guildford, 2013, 103(1): 943-949.
[18] LU F, SHEN B X, ZHANG Z H, et al.Researches on catalysts for pyrolysis of scrap tires[J]. Speciality petrochemicals, 2009, 26(4): 64-67.
[19] CAI J X, LI B, CHEN C Y, et al.Hydrothermal carbonization of tobacco stalk for fuel application[J]. Bioresoure technology, 2016, 220(30): 5-11.
[20] LIU Z G, QUEK A, HOEKMAN S K, et al.Thermogravimetric investigation of hydrochar-lignite co-combustion[J]. Bioresoure technology, 2012, 123(6): 46-52.
[21] ISLAM M A, ASIF M, HAMEED B H.Pyrolysis kinetics of raw and hydrothermally carbonized Karanj(Pongamia pinnata) fruit hulls via thermogravimetric analysis[J]. Bioresoure technology, 2015, 179(2): 27-33.
[22] LIN Y S, MA X Q, PENG X W, et al.Effect of hydrothermal carbonization temperature on combustion behavior of hydrochar fuel from paper sludge[J]. Applied thermal engineering, 2015, 91(5): 74-82.

园林废弃物水热炭燃料特性研究

RESEARCH ON FUEL PROPERTIES OF GARDEN WASTE HYDROCHARS

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 8

编辑推荐

Metrics

[1]	郑志行, 张家元, 李谦, 周浩宇. 下吸式固定床的生物质H₂O/CO₂气化数值模拟研究[J]. 太阳能学报, 2022, 43(5): 377-382.
[2]	李延吉, 伊嘉婧, 何强, 杨振涛. 碱改性HZSM-5热解生物质模型化合物影响研究[J]. 太阳能学报, 2022, 43(5): 383-390.
[3]	苏现强, 何芳, 李秀华, 高振强. 秸秆燃烧中钾逸出的几种模型的对比[J]. 太阳能学报, 2022, 43(5): 391-398.
[4]	李秀华, 苏现强, 李湘杰, 赵荣魁, 王海亮, 何芳. 秸秆燃烧过程中KCl分压蒸发模型的建立与应用[J]. 太阳能学报, 2022, 43(4): 474-479.
[5]	苏静, 牛文娟, 钟菲, 赵艺, 冯雨欣, 刘念. K₂CO₃浓度和保温时间对秸秆水热产物特性的影响[J]. 太阳能学报, 2022, 43(3): 483-491.
[6]	李天沛, 丁为民, 柴喜存, 郭彬彬, 孙杰. 酸、碱、氧化试剂与低温冻融联合预处理对高粱秸秆厌氧发酵产甲烷的影响[J]. 太阳能学报, 2022, 43(3): 492-500.
[7]	苏新凯, 黄兴强, 岳松, 余春江. 生物质循环流化床飞灰烧失特性研究[J]. 太阳能学报, 2022, 43(11): 325-330.
[8]	刘攀笏, 马莉, 曾德望, 肖睿. 基于EDEM的双螺旋反应器内物料运动与混合特性研究[J]. 太阳能学报, 2022, 43(10): 343-349.