面向碳中和的生物柴油制备及应用研究进展

陈冠益, 夏晒歌, 李婉晴, 颜蓓蓓, 赵凯歌, 程占军

太阳能学报 ›› 2022, Vol. 43 ›› Issue (9) : 343-353.

PDF(2546 KB)
欢迎访问《太阳能学报》官方网站,今天是
PDF(2546 KB)
太阳能学报 ›› 2022, Vol. 43 ›› Issue (9) : 343-353. DOI: 10.19912/j.0254-0096.tynxb.2021-0232

面向碳中和的生物柴油制备及应用研究进展

  • 陈冠益1~3, 夏晒歌1, 李婉晴1, 颜蓓蓓1, 赵凯歌1, 程占军1
作者信息 +

RESEARCH PROGRESS IN PREPARATION AND APPLICATION OF BIODIESEL FOR CARBON NEUTRALTY

  • Chen Guanyi1~3, Xia Shaige1, Li Wanqing1, Yan Beibei1, Zhao Kaige1, Cheng Zhanjun1
Author information +
文章历史 +

摘要

对制备清洁能源——生物柴油的化学催化酯交换法及其他方法,生产生物柴油的反应器及其后续开发利用等进行总结,并分析目前生物柴油在发展过程中所存在的问题,对其未来发展方向提出一些建议。

Abstract

In this paper, the chemical catalytic transesterification method and other preparation methods, and the reactors for the production of clean energy-biodiesel were summarized, the existing problems and its subsequent development and utilization in the development of biodiesel were analyzed, and some suggestions for its future development direction were put forward.

关键词

碳中和 / 生物柴油 / 酯交换 / 反应器 / 开发利用

Key words

carbon neutrality / biodiesel / transesterification / reactors / utilization

引用本文

导出引用
陈冠益, 夏晒歌, 李婉晴, 颜蓓蓓, 赵凯歌, 程占军. 面向碳中和的生物柴油制备及应用研究进展[J]. 太阳能学报. 2022, 43(9): 343-353 https://doi.org/10.19912/j.0254-0096.tynxb.2021-0232
Chen Guanyi, Xia Shaige, Li Wanqing, Yan Beibei, Zhao Kaige, Cheng Zhanjun. RESEARCH PROGRESS IN PREPARATION AND APPLICATION OF BIODIESEL FOR CARBON NEUTRALTY[J]. Acta Energiae Solaris Sinica. 2022, 43(9): 343-353 https://doi.org/10.19912/j.0254-0096.tynxb.2021-0232
中图分类号: TK513.5   

参考文献

[1] 司展, 蒋剑春, 王奎. 用于制备生物柴油的固体催化剂研究进展[J]. 生物质化学工程, 2013, 47(5): 51-56.
SI Z, JIANG J C, WANG K.Research progress of solid catalysts for biodiesel production[J]. Biomass chemical engineering, 2013, 47(5): 51-56.
[2] 姜克隽. 碳中和下先进技术研发至关重要[N]. 中国科学报, 2021-01-06.
JIANG K J. Advanced technology research and development is crucial in a carbon-neutral environment[N]. China science daily, 2021-01-06.
[3] 柴麒敏. 加快科技创新,推动我国碳中和国家建设[N]. 科技日报, 2020-10-26.
CHAI L M. Accelerate scientific and technological innovation and promote the construction of China's carbon neutral country[N]. Science and technology daily, 2020-10-26.
[4] 孟令虎, 苏海燕, 斯庆苏都, 等. 浅谈我国现有生物柴油生产工艺及发展趋势[J]. 化学工程与装备, 2019, 7: 274-276.
MENG L H, SU H Y, SI Q S D, et al. Production process and development trend of biodiesel in China[J]. Chemical engineering & equipment, 2019, 7: 274-276.
[5] 王轶辰. 生物柴油不应墙内开花墙外香[N]. 经济日报, 2021.
WANG Y C.Biodiesel should not blossom on the wall and smell on the outside[N]. Economic daily, 2021.
[6] ISSARIYAKUL T, DALAI A K.Biodiesel from vegetable oils[J]. Renewable and sustainable energy reviews, 2014, 31: 446-471.
[7] 刘天一. 浅析生物质柴油的应用[J]. 广东蚕业, 2018, 52(3): 21-22.
LIU T Y.Analysis of the application of biomass diesel oil[J]. Guangdong canye, 2018, 52(3): 21-22.
[8] FUKUDA H, KONDO A, NODA H.Biodiesel fuel production by transesterification of oils[J]. Journal of bioscience and bioengineering, 2001, 92(5): 405-416.
[9] 梁静娟, 庞宗文, 张琳, 等. 海洋假交替单胞菌抗真菌活性物质的纯化和鉴定[J]. 广东农业科学, 2014, 41(11): 114-117.
LIANG J J, PANG Z W, ZHANG L, et al.Purification and identification of antifungal compounds from marine Pseudoalteromonas ruthenica[J]. Guangdong agricultural science, 2014, 41(11): 114-117.
[10] ABDULLA R, RAVINDRA P.Immobilized Burkholderia cepacia lipase for biodiesel production from crude Jatropha curcas L oil[J]. Biomass and bioenergy, 2013, 56: 8-13.
[11] DANIELA G L, VALERIO C D S, ERIC B R, et al. Diesel-like fuel obtained by pyrolysis of vegetable oils[J]. Journal of analytical and applied pyrolysis, 2004, 71(2): 987-796.
[12] SAKA S, KUSDIANA D, MINAMI E.Non-catalytic biodiesel fuel production with supercritical methanol technologies[J]. Journal of scientific & industrial research, 2006, 65(5): 420-425.
[13] 许家胜, 阴翔宇, 张杰, 等. 生物柴油制备新工艺的研究进展[J]. 可再生能源, 2010, 28(3): 107-116.
XU J S, YIN X Y, ZHANG J, et al.Research progress of new technology for biodiesel production[J]. Renewable energy resources, 2010, 28(3): 107-116.
[14] 李飞云, 熊开峰, 王哲, 等. 固体酸催化剂在生物柴油制备中的应用研究进展[J]. 齐鲁工业大学学报, 2017, 31(1): 38-43.
LI F Y, XIONG K F, WANG Z, et al.Research progress in the application of solid acid catalysts in the preparation of biodiesel[J]. Journal of Qilu University of Technology, 2017, 31(1): 38-43.
[15] 张雅琪. 固体酸在生物柴油制备中的应用[J]. 安徽化工, 2018, 44(6): 6-10.
ZHANG Y Q.Application of solid acid in the preparation of biodiesel[J]. Anhui chemical industry, 2018, 44(6): 6-10.
[16] OLIVEIRA C F, DEZANETI L M, GARCIA F A C, et al. Esterification of oleic acid with ethanol by 12-tungstophosphoric acid supported on zirconia[J]. Applied catalysis A: general, 2010, 372(2): 153-161.
[17] BRAHMKHATRI V, PATEL A.Esterification of lauric acid with butanol-1 over H3PW12O40 supported on MCM-41[J]. Fuel, 2012, 102: 72-77.
[18] LI T F, WANG X Q, JIAO J, et al.Catalytic transesterification of Pistacia chinensis seed oil using HPW immobilized on magnetic composite graphene oxide/cellulose microspheres[J]. Renewable energy, 2018, 127: 1017-1025.
[19] XIE W L, WANG T.Biodiesel production from soybean oil transesterification using tin oxide-supported WO3 catalysts[J]. Fuel processing technology, 2013, 109: 150-155.
[20] GAO Y H. Synthesize biodiesel through SO2-4/ZrO2for use as solid super acid catalyst in biodiesel production[J]. Advanced materials research, 2014, 919-921: 2105-2108.
[21] 兰战伟, 耿欢欢, 王姗姗, 等. 改性4A分子筛催化高酸值油脂制备生物柴油[J]. 化工技术与开发, 2014, 43(11): 1-7.
LAN Z W, GENG H H, WANG S S, et al.Preparation of biodiesel from oils with high acid value by modified 4A zeolite[J]. Technology & development of chemical industry, 2014, 43(11): 1-7.
[22] BORGES L D, MOURA N N, COSTA A A, et al.Investigation of biodiesel production by HUSY and Ce/HUSY zeolites: influence of structural and acidity parameters[J]. Applied catalysis A: general, 2013, 450: 114-119.
[23] 吴志鹏, 周玉杰, 张建安, 等. 固体酸催化剂制备生物柴油研究进展[J]. 现代化工, 2008(S2): 126-129.
WU Z P, ZHOU Y J, ZHANG J A, et al.Research progress of solid acid catalyst for biodiesel production[J]. Modern chemical industry, 2008(S2): 126-129.
[24] ILGEN O.Investigation of reaction parameters, kinetics and mechanism of oleic acid esterification with methanol by using Amberlyst 46 as a catalyst[J]. Fuel processing technology, 2014, 124: 134-139.
[25] HU X L, WEI T Y, LIAO A P, et al.Use of acid cation-exchange resin for catalytic conversion of soybean acid oil to biodiesel[J]. Journal of material cycles and waste management, 2014, 18(1): 123-131.
[26] MARWAHA A, DHIR A, MAHLA S K, et al.An overview of solid base heterogeneous catalysts for biodiesel production[J]. Catalysis reviews, 2018, 60(4): 594-628.
[27] ZHANG P B, HAN Q J, FAN M M, et al.Magnetic solid base catalyst CaO/CoFe2O4 for biodiesel production: influence of basicity and wettability of the catalyst in catalytic performance[J]. Applied surface science, 2014, 317: 1125-1130.
[28] WEN L B, WANG Y, LU D L, et al.Preparation of KF/CaO nanocatalyst and its application in biodiesel production from Chinese tallow seed oil[J]. Fuel, 2010, 89(9): 2267-2271.
[29] WEI Z K, XU C L, LI B X.Application of waste eggshell as low-cost solid catalyst for biodiesel production[J]. Bioresource technology, 2009, 100(11): 2883-2285.
[30] VIRIYA-EMPIKUL N, KRASAE P, PUTTASAWAT B, et al.Waste shells of mollusk and egg as biodiesel production catalysts[J]. Bioresource technology, 2010, 101(10): 3765-3767.
[31] ROSCHAT W, SIRITANON T, KAEWPUANG T, et al.Economical and green biodiesel production process using river snail shells-derived heterogeneous catalyst and co-solvent method[J]. Bioresource technology, 2016, 209: 343-350.
[32] BANKOVIC-ILIC I B, MILADINOVIC M R, STAMENKOVIC O S, et al. Application of nano CaO-based catalysts in biodiesel synthesis[J]. Renewable and sustainable energy reviews, 2017, 72: 746-760.
[33] BORAH M J, DAS A, DAS V, et al.Transesterification of waste cooking oil for biodiesel production catalyzed by Zn substituted waste egg shell derived CaO nanocatalyst[J]. Fuel, 2019, 242: 345-354.
[34] LIU C, LYU P M, YUAN Z H, et al.The nanometer magnetic solid base catalyst for production of biodiesel[J]. Renewable energy, 2010, 35(7): 1531-1536.
[35] LIU Y L, ZHANG P B, FAN M M, et al.Biodiesel production from soybean oil catalyzed by magnetic nanoparticle MgFe2O4@CaO[J]. Fuel, 2016, 164: 314-321.
[36] HU S Y, GUAN Y P, WANG Y, et al.Nano-magnetic catalyst KF/CaO-Fe3O4 for biodiesel production[J]. Applied energy, 2011, 88(8): 2685-2690.
[37] HELWANI Z, RAMLI M, SAPUTRA E, et al.Impregnation of CaO from eggshell waste with magnetite as a solid catalyst (Fe3O4/CaO) for transesterification of palm oil off-grade[J]. Catalysts, 2020, 10(2): 164-176.
[38] LIU M Q, HUANG Y, LIU Q, et al.Ferric oxide as a support of carbide slag for effective transesterification of triglycerides in soybean oil[J]. Energy conversion and management, 2019, 198: 111785.
[39] LIU X J, HE H Y, WANG Y J, et al.Transesterification of soybean oil to biodiesel using CaO as a solid base catalyst[J]. Fuel, 2008, 87(2): 216-221.
[40] FEYZI M, NOROUZI L.Preparation and kinetic study of magnetic Ca/Fe3O4@SiO2 nanocatalysts for biodiesel production[J]. Renewable energy, 2016, 94: 579-586.
[41] EZZAH M S, LOKMAN I M, SAIMAN M I, et al.Synthesis and characterization of Fe2O3/CaO derived from Anadara Granosa for methyl ester production[J]. Energy conversion and management, 2016, 126: 124-131.
[42] AKKARAWATKHOOSITH N, KAEWCHADA A, NGAMCHARUSSRIVICHAI C, et al.Biodiesel production via interesterification of palm oil and ethyl acetate using ion-exchange resin in a packed-bed reactor[J]. Bioenergy research, 2019, 13(2): 542-551.
[43] BUASRI A, LORYUENYONG V.Continuous production of biodiesel from rubber seed oil using a packed bed reactor with BaCl2 impregnated CaO as catalyst[J]. Bulletin of chemical reaction engineering & catalysis, 2018, 13(2): 320-330.
[44] WANG X, LIU X Y, ZHAO C M, et al.Biodiesel production in packed-bed reactors using lipase-nanoparticle biocomposite[J]. Bioresource technology, 2011, 102(10): 6352-6355.
[45] GUMUS R H W I, OSARO H. Simulation model for biodiesel production using plug flow reactor: non isothermal operation[J]. International journal of engineering research and development, 2013, 6(9): 59-66.
[46] SAWANGKEAW R, BUNYAKIAT K, NGAMPRASERTSITH S.Continuous production of biodiesel with supercritical methanol: optimization of a scale-up plug flow reactor by response surface methodology[J]. Fuel processing technology, 2011, 92(12): 2285-2292.
[47] GONZALEZ J P C, GUTIERREZ P E A, MEDINA M A, et al. Effects on biodiesel production caused by feed oil changes in a continuous stirred-tank reactor[J]. Applied sciences, 2020, 10(3): 992-1015.
[48] KOUZU M, FUJIMORI A, FUKAKUSA R T, et al.Continuous production of biodiesel by the CaO-catalyzed transesterification operated with continuously stirred tank reactor[J]. Fuel processing technology, 2018, 181: 311-317.
[49] ATADASHI I M, AROUA M K, ABDUL AZIZ A R, et al. High quality biodiesel obtained through membrane technology[J]. Journal of membrane science, 2012, 421-422: 154-164.
[50] HAPOŃSKA M, NURRA C, ABELL S, et al. Membrane reactors for biodiesel production with strontium oxide as a heterogeneous catalyst[J]. Fuel processing technology, 2019, 185: 1-7.
[51] 冯斐斐, 王晓丹. 气液微反应器研究及展望[J]. 当代化工, 2017, 46(5): 943-948.
FENG F F, WANG X D.Research and prospect of gas-liquid microreactor[J]. Contemporary chemical industry, 2017, 46(5): 943-948.
[52] 郭巧玲,岳建伟. 微通道反应器制备生物柴油的工艺研究[J]. 山东化工, 2018, 48(24): 23-30.
GUO Q L, YUE J W.Preparation of biodiesel by microchannel reactor[J]. Shandong chemical industry, 2018, 48(24): 23-30.
[53] WEN Z Z, YU X H, TU S T, et al.Intensification of biodiesel synthesis using zigzag micro-channel reactors[J]. Bioresource technology, 2009, 100(12): 3054-3060.
[54] NATARAJAN Y, NABERA A, SALIKE S, et al.An overview on the process intensification of microchannel reactors for biodiesel production[J]. Chemical engineering and processing-process intensification, 2019, 136: 163-176.
[55] 周红梅, 周斌, 邱伟, 等. 柴油机燃用地沟油生物柴油性能的试验研究[J]. 小型内燃机与车辆技术, 2017, 46(3): 32-37.
ZHOU H M, ZHOU B, QIU W, et al.Experimental study on biodiesel performance of diesel engine burning gutter oil[J]. Small internal combustion engine and vehicle technique, 2017, 46(3): 32-37.
[56] 边浩毅, 贾超超, 丰延明, 等. 大豆毛油制备生物柴油在发动机上的应用[J]. 长安大学学报(自然科学版), 2013, 33(4): 121-126.
BIAN H Y, JIA C C, FENG Y M, et al.Application of biodiesel from soybean crude oil in engine[J]. Journal of Chang'an University(natural science edition), 2013, 33(4): 121-126.
[57] 郑挺. 生物柴油制备绿色增塑剂环氧脂肪酸异辛酯及应用研究[D]. 杭州: 浙江工业大学, 2019.
ZHENG T.Preparation of green plasticizer epoxidized fatty acid 2-ethylhexyl esters from biodiesel and its application[D]. Hangzhou: Zhejiang University of Technology, 2019.
[58] SRIPADA P K, SHARMA R V, DALAI A K.Comparative study of tribological properties of trimethylolpropane-based biolubricants derived from methyl oleate and canola biodiesel[J]. Industrial crops and products, 2013, 50: 95-103.
[59] CAMPANELLA A, FONTANINI C, BALTAN S M A. High yield epoxidation of fatty acid methyl esters with performic acid generated in situ[J]. Chemical engineering journal, 2008, 144(3): 466-475.
[60] MIYAKE T, MAKINO T, TANIGUCHI S I, et al.Alcohol synthesis by hydrogenation of fatty acid methyl esters on supported Ru-Sn and Rh-Sn catalysts[J]. Applied catalysis A: general, 2009, 364(1-2): 108-112.

基金

国家重点研发计划“生物质连续化制备高品质生物柴油关键技术”重点专项(2019YFB1504003)

PDF(2546 KB)

Accesses

Citation

Detail

段落导航
相关文章

/