利用受激发光特性分析n型太阳电池金属电极性能研究

张胡广, 付明, 汪小红, 吕文中

太阳能学报 ›› 2023, Vol. 44 ›› Issue (6) : 193-197.

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太阳能学报 ›› 2023, Vol. 44 ›› Issue (6) : 193-197. DOI: 10.19912/j.0254-0096.tynxb.2021-1331

利用受激发光特性分析n型太阳电池金属电极性能研究

  • 张胡广1,2, 付明1,2, 汪小红1,2, 吕文中1,2
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STUDY ON METAL ELECTRODES PERFORMANCE OF n-TYPE SOLAR CELLS BY EXCITION LUMINESCENCE CHARACTERISTICS

  • Zhang Huguang1,2, Fu Ming1,2, Wang Xiaohong1,2, Lyu Wenzhong1,2
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摘要

结合硅太阳电池电致发光(EL)和光致发光(PL)的原理分析,提出利用EL和PL图像来分析太阳电池Ag-Si接触电阻性能的新方法。制备用于n型太阳电池的两组不同体系玻璃粉的正银浆料,经丝网印刷、烧结后制得太阳电池。通过PL检测、EL检测和Ag-Si接触电阻测试,对太阳电池正银电极的欧姆接触性能进行分析,发现Pb-B-Si体系玻璃制备的正银浆料经烧结后形成的电极性能较好。通过对玻璃粉的同步热分析仪(TGA-DSC)分析,发现转变温度Tg较低的玻璃粉制备的电极浆料所形成的电极接触性能较好。

Abstract

Combining the principle analysis of the EL and PL of silicon solar cells, a new method using EL and PL images to analyze the Ag-Si contact resistance performance of the solar cells is proposed. Two groups of front-side silver pastes with different systems glass powder for n-type solar cells are prepared. The solar cells are fabricated after screen printing and sintering. The ohmic contact performance of the front-side silver electrode is analyzed via PL test, EL test and Ag-Si contact resistance test. It is found that the front-side silver paste of the Pb-B-Si systems glass powder has better electrode performance after sintering. The performance of the glass powder is analyzed via TGA-DSC, and it is found that the contact performance of the electrode formed by the electrode paste prepared from the glass powder with lower Tg (glass transition temperature) is better.

关键词

太阳电池 / 电致发光 / 光致发光 / 电极 / 接触电阻

Key words

solar cells / electroluminescence / photoluminescence / electrode / contact resistance

引用本文

导出引用
张胡广, 付明, 汪小红, 吕文中. 利用受激发光特性分析n型太阳电池金属电极性能研究[J]. 太阳能学报. 2023, 44(6): 193-197 https://doi.org/10.19912/j.0254-0096.tynxb.2021-1331
Zhang Huguang, Fu Ming, Wang Xiaohong, Lyu Wenzhong. STUDY ON METAL ELECTRODES PERFORMANCE OF n-TYPE SOLAR CELLS BY EXCITION LUMINESCENCE CHARACTERISTICS[J]. Acta Energiae Solaris Sinica. 2023, 44(6): 193-197 https://doi.org/10.19912/j.0254-0096.tynxb.2021-1331
中图分类号: TM914.4   

参考文献

[1] SCHMIGA C, NAGEL H, SCHMIDT J, et a1. 19% efficient n-type Czochralski silicon solar cells with screen-printed aluminium-alloyed rear emitter[J]. Progress in photovoltaics research and applications, 2006, 14(6): 533-539.
[2] WÜRFEL P. Physics of solar cells: from principles to new concepts[M]. Weinheim: Wiley-VCH, 2005: 65-67.
[3] TRUPKE T, BARDOS R A, ABBOTT M D, et a1.Suns-photoluminescence:contactless determination of current-voltage characteristics of silicon wafers[J]. Applied physics letters, 2005, 87(9): 093503.
[4] 娄世殊. 晶硅太阳电池的受激发光成像检测方法研究[D]. 北京: 中国科学院大学, 2016.
LOU S S.Investigation of excited luminescence imaging testing methods for silicon solar cells[D]. Beijing: University of Chinese Academy of Sciences, 2016.
[5] 柳效辉, 徐林, 肖晨江, 等. 晶体硅太阳电池电致发光的研究[J]. 太阳能学报, 2011, 32(6): 822-824.
LIU X H, XU L, XIAO C J, et al.Study of the electrolunm-inescence characterization of crystalline silicon solar cells[J]. Acta energiae solaris sinica, 2011, 32(6): 822-824.
[6] TRUPKE T, BARDOS R A, ABBOTT M D.Self-consistent calibration of photoluminescence and photoconductance lifetime measurements[J]. Applied physics letters, 2005, 87(18): 184102.
[7] 周洪. 晶体硅太阳能电池EL测试仪及电池老化特性研究[D]. 武汉: 华中科技大学, 2018.
ZHOU H.Study on the EL tester and aging characteristics of crystalline silicon solar cells[D]. Wuhan: Huazhong University of Science & Technology, 2018.

基金

湖北省自然科学基金(2019CFB677)

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