EL检测PERC电池中间缺陷成因及改善方法的研究

夏中高, 彭平, 景彦姣, 陈磊, 王文静, 周春兰

太阳能学报 ›› 2023, Vol. 44 ›› Issue (6) : 198-203.

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太阳能学报 ›› 2023, Vol. 44 ›› Issue (6) : 198-203. DOI: 10.19912/j.0254-0096.tynxb.2022-0069

EL检测PERC电池中间缺陷成因及改善方法的研究

  • 夏中高1, 彭平1, 景彦姣1, 陈磊1, 王文静2, 周春兰2
作者信息 +

STUDY ON CAUSES AND IMPROVEMENT METHODS OF INTERMEDIATE DEFECTS IN PERC CELLS DETECTED BY EL

  • Xia Zhonggao1, Peng Ping1, Jing Yanjiao1, Chen Lei1, Wang Wenjing2, Zhou Chunlan2
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摘要

电致发光(EL)检测是PERC太阳电池生产中常用的缺陷检测方法,其中位于太阳电池中间位置缺陷的降级占EL检测不良降级的50%以上,成为了各大太阳电池制造企业EL检测良率突破99%的主要障碍。为找到缺陷的成因并改善这种问题,进而提升太阳电池的质量降低制造成本,该文对太阳电池EL检测下中间位置出现缺陷的原因进行分析研究。通过QE测试和元素成分分析排除由硅片质量和杂质污染所引起缺陷的可能性,再结合电化学电容-电压方法(ECV)及扫描电镜(SEM)测试,确定PERC电池中间位置缺陷的产生是由于扩散工艺表面杂质浓度过高所导致的。该文针对缺陷成因提出有效的解决方案有助于提升太阳电池的质量及EL检测良率。

Abstract

Electroluminescence (EL) inspection is a common defect detection method in PERC solar cell production, in which degradation of defect located in the middle of the cell accounts for more than 50% of total undesirable degradation detected by EL and has become a major obstacle for major PV manufacturing companies to break 99% of EL inspection yields. In order to find the causes of defects and improve this problem, improve the quality of solar cells and reduce cell manufacturing costs, this paper analyses and investigates the causes of defects that occur in the middle of the cell under EL inspection. Using quantum efficiency test and elemental analysis to rule out the possibility of defects caused by wafer quality and impurity contamination, combined with electrochemical capacitance-voltage(ECV) and scanning electron microscopy(SEM) tests, it is determined that the defects in the intermediate position of PERC cells are caused by a too high concentration of impurities on the surface of the diffusion process. Effective solutions are proposed to address the causes of defects, which can help to improve the quality of solar cells and increase the yield of cell EL inspection.

关键词

PERC电池 / 缺陷 / 表面掺杂浓度 / EL / 绒面形貌

Key words

PERC cell / defect / surface doping concentration / EL / surface morphology of texture

引用本文

导出引用
夏中高, 彭平, 景彦姣, 陈磊, 王文静, 周春兰. EL检测PERC电池中间缺陷成因及改善方法的研究[J]. 太阳能学报. 2023, 44(6): 198-203 https://doi.org/10.19912/j.0254-0096.tynxb.2022-0069
Xia Zhonggao, Peng Ping, Jing Yanjiao, Chen Lei, Wang Wenjing, Zhou Chunlan. STUDY ON CAUSES AND IMPROVEMENT METHODS OF INTERMEDIATE DEFECTS IN PERC CELLS DETECTED BY EL[J]. Acta Energiae Solaris Sinica. 2023, 44(6): 198-203 https://doi.org/10.19912/j.0254-0096.tynxb.2022-0069
中图分类号: TM914.4   

参考文献

[1] DING D, ZHUANG Y F, CUI Y F, et al.Application of phosphorus-doped polysilicon-based full-area passivating contact on the front textured surface of p-type silicon[J]. Physica status solidi, 2021, 15(1): 2000455.
[2] YUAN S Z, CUI Y F, ZHUANG Y F, et al.Passivated emitter and rear cell silicon solar cells with a front polysilicon passivating contacted processing selective emitter[J]. Physica status solidi, 2021, 15(7): 2100057.
[3] 李景华, 林晨, 孙柯. 晶体硅太阳电池及组件EL测试介绍[J]. 科技致富向导, 2012, 14: 183.
LI J H, LIN C, SUN K.Introduction to testing of crystalline silicon solar cells and modules[J]. Wizard magazine rich technology, 2012, 14: 183.
[4] 陈晓玉, 刘彤, 刘京明, 等. 晶硅太阳电池黑斑分析[J]. 半导体光电, 2017, 38(1): 21-25.
CHEN X Y, LIU T, LIU J M, et al.Black spot analysis of crystalline silicon solar cells[J]. Semiconductor optoelectronics, 2017, 38(1): 21-25.
[5] 林星星, 杨党强. “死层”掺杂浓度和厚度对太阳能电池性能的影响[J]. 上海电机学院学报, 2019, 22(1): 1-5.
LIN X X, YANG D Q.Effects of the doping concentration and depth of “the dead layer”on silicon solar cells[J]. Journal of Shanghai Dianji University, 2019, 22(1): 1-5.
[6] 豆维江, 秦应雄, 巨小宝, 等. 多晶硅片反应离子刻蚀制绒扩散工艺的匹配性[J]. 光子学报, 2013, 42(6): 649-653.
DOU W J, QIN Y X, JU X B, et al.Diffusion processing and its matching property of multicrystalline silicon solar cells through reactive ion etching texturing[J]. Acta photonica sinica, 2013, 42(6): 649-653.
[7] 刘文峰, 周子游, 黄海龙, 等. PERC太阳电池发射极表面优化设计与模拟[J]. 太阳能, 2019(8): 29-35.
LIU W F, ZHOU Z Y, HUANG H L, et al.PERC solar cell emitter surface optimization design and simulation[J]. Solar energy, 2019(8): 29-35.
[8] 李雪方, 元江博. 单晶硅电池制绒工艺研究[J]. 山西化工, 2020, 40(4): 3-4.
LI X F, YUAN J B.Monocrystalline silicon cell texturing process research[J]. Shanxi chemical industry, 2020, 40(4): 3-4.
[9] 王利果, 张晓丹, 王奉友, 等. 不同形貌的金字塔结构对硅片表面钝化和异质结太阳电池的影响[J]. 物理化学学报, 2014, 30(9): 1758-1763.
WANG L G, ZHANG X D, WANG F Y, et al.Influence of different pyramidal structural morphologies of crystalline silicon wafers for surface passivation and heterojunction solar cells[J]. Acta physico-chimica sinica, 2014, 30(9): 1758-1763.
[10] TONG R, ZHANG W P, KE X M, et al.Influence of surface structure on the performance of mono-like Si PERC solar cell[J]. Materials science in semiconductor processing, 2021, 126: 105662.
[11] 李旺, 唐鹿, 田娅晖, 等. 低表面浓度磷掺杂的高方阻 P-N结发射极制备工艺[J]. 人工晶体学报, 2022, 51(1): 132-138.
LI W, TANG L, TIAN Y H, et al.Process of preparing high sheet resistance P-N junction emitter with low surface phosphorus doping concentration[J]. Journal of synthetic crystals, 2022, 51(1): 132-138.

基金

河南省中国科学院科技成果转移转化项目(2020108)

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