新型纸浆污泥生物炭基催化剂的制备及其催化合成生物柴油研究

赵丹丹; 赵伟; 单锐; 陈德珍; 袁浩然; 陈勇

doi:10.19912/j.0254-0096.tynxb.2022-0722

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太阳能学报 ›› 2023, Vol. 44 ›› Issue (9) : 432-439. DOI: 10.19912/j.0254-0096.tynxb.2022-0722

新型纸浆污泥生物炭基催化剂的制备及其催化合成生物柴油研究

赵丹丹^1,2, 赵伟³, 单锐², 陈德珍¹, 袁浩然^1,2, 陈勇^1,2

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STUDY ON PREPARATION OF MODIFIED WASTE PAPER PULP BIOCHAR-BASED CATALYST AND ITS CATALYTIC APPLICATION FOR BIODIESEL PRODUCTION

Zhao Dandan^1,2, Zhao Wei³, Shan Rui², Chen Dezhen¹, Yuan Haoran^1,2, Chen Yong^1,2

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摘要

以纸浆污泥生物炭为载体制备固体碱催化剂,并将其应用于生物柴油的制备。催化剂的物理化学性质通过热重分析（TG）、扫描电子显微镜及X射线能谱分析（SEM-EDS）、傅里叶变换红外光谱（FTIR）、X射线衍射（XRD）、N₂吸附/脱附和CO2-TPD进行表征。结果表明：由于30K/PPSB-600催化剂的总碱度最高,具有非常好的的催化性能（生物柴油最大产率为98.5％）。此外,对催化剂的稳定性和利用周期性进行多次实验。通过8次回收实验后,新催化剂仍具有较高的催化性能（生物柴油产率为80％）,其中少量失去催化活性的原因是K⁺的流失。

Abstract

In this paper, pulp & paper sludge biochar is used as a carrier to prepare a solid base catalyst and applied to the preparation of biodiesel. The physicochemical properties of the catalyst were analyzed by thermogravimetric analysis （TGA）, scanning electron microscope & energy dispersive spectrometer （SEM-EDS）, Fourier transform infrared spectroscopy （FTIR）, X-ray diffraction （XRD）, N₂ adsorption/desorption and CO₂-TPD for characterization. The results show that 30K/PPSB-600 has the highest total alkalinity, and it has excellent catalytic activity （maximum biodiesel yield is 98.5%）. In addition, the stability and reusability of the catalyst were also examined. After 8 times of repeated use, the catalyst still has high catalytic activity （biodiesel yield is 80%）. The small amount of catalyst deactivation is mainly due to the loss of K⁺ ions.

导出引用

赵丹丹, 赵伟, 单锐, 陈德珍, 袁浩然, 陈勇. 新型纸浆污泥生物炭基催化剂的制备及其催化合成生物柴油研究[J]. 太阳能学报. 2023, 44(9): 432-439 https://doi.org/10.19912/j.0254-0096.tynxb.2022-0722

Zhao Dandan, Zhao Wei, Shan Rui, Chen Dezhen, Yuan Haoran, Chen Yong. STUDY ON PREPARATION OF MODIFIED WASTE PAPER PULP BIOCHAR-BASED CATALYST AND ITS CATALYTIC APPLICATION FOR BIODIESEL PRODUCTION[J]. Acta Energiae Solaris Sinica. 2023, 44(9): 432-439 https://doi.org/10.19912/j.0254-0096.tynxb.2022-0722

中图分类号： X705

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