将片状氧化石墨烯与相变材料微胶囊进行混合,制备成光热悬浮液,对其光学性能和光热转换性能进行探究,并分析氧化石墨烯对相变材料微胶囊光热性能的影响机理。结果表明,相较于无氧化石墨烯的相变材料微胶囊悬浮液,添加氧化石墨烯的复合悬浮液的光学性能和光热转换性能均有明显提升,在0.1%的相变材料微胶囊悬浮液中添加0.03%的氧化石墨烯,使其在特定波长下的消光系数提升522.30%,添加0.1%氧化石墨烯时室内光热实验的温升和光热效率达到最高,分别为63.7 ℃和57.49%,在室外光热实验中温度提升59.2 ℃。
Abstract
The sheet GO was mixed with the phase change material microcapsule and prepared into a photothermal suspension, and its optical properties and photothermal conversion properties were explored and analyzed mechanism of GO effects on the photothermal properties of phase transition materials. The results show that the optical performance and photothermal conversion performance of the compound suspension are significantly improved compared with the microcapsule suspension without GO. The addition of 0.03% graphene oxide to the microcapsule suspension of 0.1% phase change material increased the extinction coefficient at a specific wavelength by 522.30%. The temperature rise and photothermal efficiency of the indoor photothermal experiments were the highest when 0.1% GO was added, which were 63.7 ℃ and 57.49%, the temperature was increased by 59.2 ℃ in outdoor photothermal experiments.
关键词
氧化石墨烯 /
相变材料 /
储热 /
太阳能吸收器 /
太阳能 /
太阳热
Key words
graphene oxide /
phase change materials /
heat storage /
solar absorbers /
solar energy /
solar heating
{{custom_sec.title}}
{{custom_sec.title}}
{{custom_sec.content}}
参考文献
[1] 王子青, 栾敬德. 杂化壳相变微胶囊的制备与热性能研究[J]. 太阳能学报, 2023, 44(9): 527-531.
WANG Z Q, LUAN J D.Preparation and thermal properties of hybrid shell phase change microcapsules[J]. Acta energiae solaris sinica, 2023, 44(9): 527-531.
[2] WANG Z H, QU J, ZHANG R M, et al.Photo-thermal performance evaluation on MWCNTs-dispersed microencapsulated PCM slurries for direct absorption solar collectors[J]. Journal of energy storage, 2019, 26: 100793.
[3] RAJABIFAR B.Enhancement of the performance of a double layered microchannel heatsink using PCM slurry and nanofluid coolants[J]. International journal of heat and mass transfer, 2015, 88: 627-635.
[4] 吴贺利. 菲涅尔太阳能聚光器研究[D]. 武汉: 武汉理工大学, 2010.
WU H L.Study on fresnel solar concentrator[D]. Wuhan: Wuhan University of Technology, 2010.
[5] HAZRA S K, GHOSH S, NANDI T K.Photo-thermal conversion characteristics of carbon black-ethylene glycol nanofluids for applications in direct absorption solar collectors[J]. Applied thermal engineering, 2019, 163: 114402.
[6] YANG R, LI X K, YIN F, et al.The mechanism of enhanced photothermal conversion of low-dimensional plasmonic nanofluids with LFPs resonance[J]. International journal of heat and mass transfer, 2023, 208: 124056.
[7] 闫全英, 王晨羽, 梁高金, 等. 用添加剂强化有机相变材料导热性能的研究[J]. 太阳能学报, 2021, 42(9): 205-209.
YAN Q Y, WANG C Y, LIANG G J, et al.Study on enhancing thermal conductivity of organic phase change materials with additives[J]. Acta energiae solaris sinica, 2021, 42(9): 205-209.
[8] NOBAKHT HASSANLOUEI R, JAHANGIRI M, DAWI E A, et al.The new correlation for viscosity of synthesized viscoelastic-based nanoliquid using functionalized MWCNT: stability, thermal conductivity, and rheology[J]. Alexandria engineering journal, 2023, 72: 495-509.
[9] SAVCHUK O A, CARVAJAL J J, MASSONS J, et al.Determination of photothermal conversion efficiency of graphene and graphene oxide through an integrating sphere method[J]. Carbon, 2016, 103: 134-141.
[10] WANG D B, JIA Y L, HE Y, et al.Photothermal efficiency enhancement of a nanofluid-based direct absorption solar collector utilizing magnetic nano-rotor[J]. Energy conversion and management, 2019, 199: 111996.
[11] 郑开明, 徐荣吉, 王瑞祥, 等. 工质表面张力和黏度对脉动热管启动及传热热阻的影响[J]. 化工进展, 2017, 36(8): 2816-2821.
ZHENG K M, XU R J, WANG R X, et al.Influence of surface tension and viscosity on the start-up time and thermal resistance of pulsating heat pipe[J]. Chemical industry and engineering progress, 2017, 36(8): 2816-2821.
[12] ABD-ALLA A M, ABO-DAHAB S M, ALBALAWI M M. Effect of variable viscosity on peristaltic flow of second order fluid with heat and mass transfer[J]. Journal of computational and theoretical nanoscience, 2015, 12(10): 3110-3117.
[13] 王文龙. 纳米流体在封闭腔内的自然对流传热特性研究[D]. 杭州: 中国计量学院, 2014.
WANG W L.Study on natural convection heat transfer characteristics of nanofluid in closed cavity[D]. Hangzhou: China University of Metrology, 2014.
[14] KHRAPAK S A, KHRAPAK A G.Correlations between the shear viscosity and thermal conductivity coefficients of dense simple liquids[J]. JETP letters, 2021, 114(9): 540-544.
[15] LU P J, CONRAD J C, WYSS H M, et al.Fluids of clusters in attractive colloids[J]. Physical review letters, 2006, 96(2): 028306.
基金
蛙卵仿生结构水基纳米流体光热性能及转子扰流强化集热技术研究(52176175)