乙酸钾修饰界面用于高效稳定的钙钛矿太阳电池

户立文; 胡隆生; 杨亿凡; 李国龙

doi:10.19912/j.0254-0096.tynxb.2023-1210

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太阳能学报 ›› 2024, Vol. 45 ›› Issue (4) : 51-58. DOI: 10.19912/j.0254-0096.tynxb.2023-1210

乙酸钾修饰界面用于高效稳定的钙钛矿太阳电池

户立文¹, 胡隆生², 杨亿凡³, 李国龙¹

作者信息 +

POTASSIUM ACETATE MODIFIED INTERFACE FOR EFFICIENT AND STABLE PEROVSKITE SOLAR CELLS

Hu Liwen¹, Hu Longsheng², Yang Yifan³, Li Guolong¹

Author information +

文章历史 +

摘要

使用乙酸钾（KAc）修饰电子传输层,正置结构的SnO₂/perovskite界面使用其具有的羧基和碱金属阳离子调节能级。研究发现,KAc薄膜的引入会对钙钛矿薄膜产生一定的表面陷阱钝化作用,表现出非辐射复合的减少以及体内和界面电荷复合的抑制。此外,调节钙钛矿晶体的生长,产生晶粒尺寸从450 nm增至600 nm且无针孔的钙钛矿薄膜,缺陷密度显著降低。结果表明,通过使用KAc来修饰电子传输层,可明显减少SnO₂电子传输层的缺陷及能级差;优化后的太阳电池效率提高7.63%,量子效率（IPCE）从87.3%增大到90.1%。

Abstract

In the paper, potassium acetate（KAc） is used to modify the SnO₂ electron transport layer, thus regulating the energy level alignment of the SnO₂/perovskite interface. In addition, the introduction of KAc film passivates perovskite film to attenuate the probability of non-radiative recombination and inhibits the bulk and interface charge recombination. Meanwhile, the introduction of KAc film improves the growth process of perovskite crystals. Perovskite films with grain size increase from 450 nm to about 600 nm and without pinholes are produced. Therefore, inserting KAc as the modification layer significantly reduces the defect of the SnO₂ electron transport layer and optimizes energy level difference as well. As a result, the efficiency of the optimized solar cell is increased by 7.63% compared with that of the referred device, and the IPCE is increased from 87.3% to 90.1%.

导出引用

户立文, 胡隆生, 杨亿凡, 李国龙. 乙酸钾修饰界面用于高效稳定的钙钛矿太阳电池[J]. 太阳能学报. 2024, 45(4): 51-58 https://doi.org/10.19912/j.0254-0096.tynxb.2023-1210

Hu Liwen, Hu Longsheng, Yang Yifan, Li Guolong. POTASSIUM ACETATE MODIFIED INTERFACE FOR EFFICIENT AND STABLE PEROVSKITE SOLAR CELLS[J]. Acta Energiae Solaris Sinica. 2024, 45(4): 51-58 https://doi.org/10.19912/j.0254-0096.tynxb.2023-1210

中图分类号： TM914.4

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