生物质基酯类燃料联产化学品的技术经济性评价

李学琴, 王志伟, 刘鹏, 吴幼青, 区境深, 雷廷宙

太阳能学报 ›› 2025, Vol. 46 ›› Issue (2) : 10-17.

PDF(2890 KB)
欢迎访问《太阳能学报》官方网站,今天是
PDF(2890 KB)
太阳能学报 ›› 2025, Vol. 46 ›› Issue (2) : 10-17. DOI: 10.19912/j.0254-0096.tynxb.2023-1617

生物质基酯类燃料联产化学品的技术经济性评价

  • 李学琴1~3, 王志伟1,2, 刘鹏3, 吴幼青3, 区境深4, 雷廷宙3
作者信息 +

TECHNO-ECONOMIC EVALUATION OF BIOMASS-BASED ESTER FUEL CO-PRODUCED CHEMICALS

  • Li Xueqin1~3, Wang Zhiwei1,2, Liu Peng3, Wu Youqing3, Ou Jingshen4, Lei Tingzhou3
Author information +
文章历史 +

摘要

为探究生物质液体燃料全生命周期经济性及替代可能性,以乙酰丙酸酯为研究对象,以年消耗2000 t甘蔗渣制备乙酰丙酸酯规模化生产系统为例,设计生产生物质基酯类燃料的系统边界及工艺过程,建立全生命周期经济性分析模型,进行综合成本估算及经济性分析。通过动态分析指标深入研究生物质基酯类燃料全生命周期的经济性,获得生物质水解制备乙酰丙酸酯的经济效益结果,明确影响生产成本的关键因素并估算生产成本的不确定性;整个工艺过程表现出良好的经济性和应用前景,可促进生物质基乙酰丙酸酯的清洁生产,为生物质基酯类燃料联产化学品技术规模化运行提供理论支撑。

Abstract

In order to explore the economic assessment of the whole life cycle of biomass liquid fuel, this paper takes levulinate as the research object and takes the large-scale production system for the preparation of levulinate with annual consumption of 2000 t of bagasse were an example. The system boundary and process of bagasse hydrolysis to produce biomass-based ester fuels were designed creatively, and the whole life cycle economic analysis model was established, and the comprehensive cost estimation and economic analysis were carried out. Through the dynamic index, the economy of whole life cycle of biomass-based ester fuel was deeply analyzed, and the economic results were obtained. The key factors affecting production cost were identified and the uncertainty of production cost was estimated. As the results, the whole process shows good economy and application prospect. It provides the theoretical support for the large-scale technology of biomass-based ester fuel co-producing chemicals, and promotes the clean production of biomass-based levulinate.

关键词

生物质 / 生命周期评价 / 酯类燃料 / 经济性分析 / 综合成本估算

Key words

biomass / life cycle assessement / ester fuel / economical analysis / comprehensive cost estimation

引用本文

导出引用
李学琴, 王志伟, 刘鹏, 吴幼青, 区境深, 雷廷宙. 生物质基酯类燃料联产化学品的技术经济性评价[J]. 太阳能学报. 2025, 46(2): 10-17 https://doi.org/10.19912/j.0254-0096.tynxb.2023-1617
Li Xueqin, Wang Zhiwei, Liu Peng, Wu Youqing, Ou Jingshen, Lei Tingzhou. TECHNO-ECONOMIC EVALUATION OF BIOMASS-BASED ESTER FUEL CO-PRODUCED CHEMICALS[J]. Acta Energiae Solaris Sinica. 2025, 46(2): 10-17 https://doi.org/10.19912/j.0254-0096.tynxb.2023-1617
中图分类号: TK6    TK9   

参考文献

[1] GIRISUTA B, JANSSEN L P B M, HEERES H J. Green chemicals: a kinetic study on the conversion of glucose to levulinic acid[J]. Chemical engineering research and design, 2006, 84(5): 339-349.
[2] 林鹿, 薛培俭, 庄军平. 生物质基乙酰丙酸化学与技术[M]. 北京: 化学工业出版社, 2009.
LIN L, XUE P J, ZHUANG J P, et al.Biomass based levulinic acid chemistry and technology[M]. Beijing: Chemical Industry Press, 2009.
[3] 常春, 马晓建, 岑沛霖. 新型绿色平台化合物乙酰丙酸的生产及应用研究进展[J]. 化工进展, 2005, 24(4): 350-356.
CHANG C, MA X J, CEN P L.Advances in production and application of levulinic acid: new type green platform chemical[J]. Chemical industry and engineering progress, 2005, 24(4): 350-356.
[4] 张挺, 常春. 生物质制备乙酰丙酸酯类转化路径的研究进展[J]. 化工进展, 2012, 31(6): 1224-1230.
ZHANG T, CHANG C.Advances in the route of levulinate esters from biomass[J]. Chemical industry and engineering progress, 2012, 31(6): 1224-1230.
[5] LANGE J P, VANβDEβGRAAF W, HAAN R. Conversion of furfuryl alcohol into ethyl levulinate using solid acid catalysts[J]. Chemsuschem, 2010, 2(6): 437-441.
[6] FANG Q, HANNA M A.Experimental studies for levulinic acid production from whole kernel grain sorghum[J]. Bioresource technology, 2002, 81(3): 187-192.
[7] 徐桂转, 马俊军, 岳建芝. 生物质制备乙酰丙酸的影响因素研究[J]. 河南农业大学学报, 2007, 41(5): 584-587.
XU G Z, MA J J, YUE J Z.Factors influencing the production of levulinic acid from biomass[J]. Journal of Henan Agricultural University, 2007, 41(5): 584-587.
[8] 常春, 马晓建, 岑沛霖. 小麦秸秆制备新型平台化合物-乙酰丙酸的工艺研究[J]. 农业工程学报, 2006, 22(6): 161-164.
CHANG C, MA X J, CEN P L.Technology for production of levulinic acid as new platform chemical from wheat straw[J]. Transactions of the Chinese Society of Agricultural Engineering, 2006, 22(6): 161-164.
[9] 李湘苏. WO3/ZrO2固体酸水解稻谷壳制备乙酰丙酸的优化研究[J]. 江苏农业科学, 2012, 40(9): 267-268.
LI X S.Optimization study on the preparation of levulinic acid from rice husks by WO3/ZrO2 solid acid hydrolysis[J]. Jiangsu agricultural sciences, 2012, 40(9): 267-268.
[10] 李静, 王君, 张晔, 等. 酸催化水解蔗糖制取乙酰丙酸[J]. 化工进展, 2012, 31(S1): 57-59.
LI J, WANG J, ZHANG Y, et al.Study on production of levulinic acid by acid catalytic hydrolysis of sucrose[J]. Chemical industry and engineering progress, 2012, 31(S1): 57-59.
[11] CHEN Z, LI X Q, WANG Z W, et al.Techno-economic and whole life cycle assessment of ester fuels production from agricultural waste via hydrothermal liquefaction[J]. Industrial crops and products, 2023, 192: 116096.
[12] DHARNE S, BOKADE V V.Esterification of levulinic acid to n-butyl levulinate over heteropolyacid supported on acid-treated clay[J]. Journal of natural gas chemistry, 2011, 20(1): 18-24.
[13] DIBANET. Production of sustainable diesel-miscible biofuels from the residues and wastes of Europe And Latin America [EB/OL]. https://biomass-roup.njau.edu.cn/info/1016/1853.htm
[14] 张亮. 车用燃料煤基二甲醚的生命周期能源消耗、环境排放与经济性研究[D]. 上海: 上海交通大学, 2007.
ZHANG L.Study of life cycle energy consumption, environmental emission and economics of coal-based dimethyl ehter as vehicle fuel[D]. Shanghai: Shanghai Jiao Tong University, 2007.
[15] FURUHOLT E.Life cycle assessment of gasoline and diesel[J]. Resources, conservation and recycling, 1995, 14(3-4): 251-263.
[16] 李铮. 生物质基乙酰丙酸(酯)转化为液体燃料与化学品的研究[D]. 厦门: 厦门大学, 2018.
LI Z.Conversion of biomass-derived levulinic acid (esters) toliquid fuel and chemicals[D]. Xiamen: Xiamen University, 2018.
[17] 王志伟. 生物质基乙酰丙酸乙酯混合燃料动力学性能研究[D]. 郑州: 河南农业大学, 2013.
WANG Z W.Study on dynamics performance of biomass based ethyl levulinate blended fuels[D]. Zhengzhou: Henan Agricultural University, 2013.
[18] 雷廷宙, 王志伟, 刘亮, 等. 基于灰色关联的乙酰丙酸乙酯-柴油燃烧排放分析[J]. 河南科学, 2013, 31(3): 342-347.
LEI T Z, WANG Z W, LIU L, et al.Grey relation analysis for combustion and emissions characteristics of engine using ethyl levulinate-diesel[J]. Henan science, 2013, 31(3): 342-347.
[19] KALTSCHMITT M, REINHARDT G A, STELZER T.Life cycle analysis of biofuels under different environmental aspects[J]. Biomass and bioenergy, 1997, 12(2): 121-134.
[20] QU J S, LEI T Z, SUN T L, et al.Exergy analysis of biomass-based ethyl levulinate fuel for whole life cycle[J]. Journal of biobased materials and bioenergy, 2023, 17(1): 105-113.
[21] CHEN Z, LEI T Z, WANG Z W, et al.Environmental and economic impacts of biomass liquid fuel conversion and utilization: a review[J]. Journal of biobased materials and bioenergy, 2022, 16(2): 163-175.
[22] GUNUKULA S, DAIGNEAULT A, BOATENG A A, et al.Influence of upstream, distributed biomass-densifying technologies on the economics of biofuel production[J]. Fuel, 2019, 249: 326-333.
[23] USLU A, FAAIJ A P C, BERGMAN P C A. Pre-treatment technologies, and their effect on international bioenergy supply chain logistics. Techno-economic evaluation of torrefaction, fast pyrolysis and pelletisation[J]. Energy, 2008, 33(8): 1206-1223.
[24] DYJAKON A.Harvesting and baling of pruned biomass in apple orchards for energy production[J]. Energies, 2018, 11(7): 1-16.
[25] BHUTTO A W, QURESHI K, HARIJAN K, et al.Insight into progress in pre-treatment of lignocellulosic biomass[J]. Energy, 2017, 122: 724-745.
[26] 潘小天, 仲兆平, 汪维, 等. 不同生物质原料的气化合成制航煤的环境影响评价[J]. 太阳能学报, 2023, 44(5): 10-16.
PAN X T, ZHONG Z P, WANG W, et al.Environmental impact assessment of gasification synthesis of different biomass for production of jet fuel[J]. Acta energiae solaris sinica, 2023, 44(5): 10-16.
[27] 邓志雅, 向夏楠, 彭德用, 等. 基于热效率和<inline-graphic xlink:href="-46-2-10.xml/img_1.png"/>效率分析的循环流化床生物质气化规律研究[J]. 太阳能学报, 2023, 44(3): 284-290.
DENG Z Y, XIANG X N, PENG D Y, et al.Study on circulating fluidied bed biomass gasification law based on energy and exergy analysis[J]. Acta energiae solaris sinica, 2023, 44(3): 284-290.
[28] 朱祺. 生物柴油的生命周期能源消耗、环境排放与经济性研究[D]. 上海: 上海交通大学, 2008.
ZHU Q.Study of life cycle energy consumption,enviromental emission and economics of biodiesel[D]. Shanghai: Shanghai Jiao Tong University, 2008.
[29] BULL S R.Renewable alternative fuels: alcohol production from lignocellulosic biomass[J]. Renewable energy, 1994, 5(5): 799-806.
[30] CAMOBRECO V, SHEEHAN J, DUFFIELD J, et al.Understanding the life-cycle costs and environmental profile of biodiesel and petroleum diesel fuel[J]. SAE technical paper, 2000, 2000-01-1487. Understanding the life-cycle costs and environmental profile of biodiesel and petroleum diesel fuel[J]. SAE technical paper, 2000, 2000-01-1487. http://doi.org/.10.4271/2000-01-1487.
[31] DE LAPORTE A V, RIPPLINGER D G. The effects of site selection, opportunity costs and transportation costs on bioethanol production[J]. Renewable energy, 2019, 131: 73-82.
[32] 胡志远, 谭丕强, 楼狄明, 等. 不同原料制备生物柴油生命周期能耗和排放评价[J]. 农业工程学报, 2006, 22(11): 141-146.
HU Z Y, TAN P Q, LOU D M, et al.Assessment of life cycle energy consumption and emissions for several kinds of feedstock based biodiesel[J]. Transactions of the Chinese Society of Agricultural Engineering, 2006, 22(11): 141-146.
[33] 易红宏, 朱永青, 王建昕, 等. 含氧生物质燃料的生命周期评价[J]. 环境科学, 2005, 26(6): 28-32.
YI H H, ZHU Y Q, WANG J X, et al.Life cycle assessment on oxygen biofuels[J]. Environmental science, 2005, 26(6): 28-32.

基金

航空替代燃料可持续评价(MJ-2020-D-09); 国家重点研发计划(2022YFB4201901).

PDF(2890 KB)

Accesses

Citation

Detail

段落导航
相关文章

/