新型低熔点三元混合硝酸盐高温腐蚀行为研究

韩昕龙, 张春琳, 鹿院卫, 高祺, 王元媛, 吴玉庭

太阳能学报 ›› 2025, Vol. 46 ›› Issue (8) : 309-314.

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太阳能学报 ›› 2025, Vol. 46 ›› Issue (8) : 309-314. DOI: 10.19912/j.0254-0096.tynxb.2024-0500

新型低熔点三元混合硝酸盐高温腐蚀行为研究

  • 韩昕龙1, 张春琳2, 鹿院卫1, 高祺1, 王元媛1, 吴玉庭1
作者信息 +

RESEARCH ON HIGH TEMPERATURE CORROSION BEHAVIOR OF NOVEL LOW MELTING POINT TERNARY MIXED NITRATES

  • Han Xinlong1, Zhang Chunlin2, Lu Yuanwei1, Gao Qi1, Wang Yuanyuan1, Wu Yuting1
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摘要

为探究新型低熔点三元混合硝酸盐的高温腐蚀特性,该文采取失重法研究347H和316L不锈钢在500 ℃和550 ℃两种温度下三元硝酸盐中的静态腐蚀行为。结果表明,随着腐蚀温度的升高,347H和316L不锈钢的腐蚀速率都随之增高;相同温度下,随着浸泡时间的增加347H和316L不锈钢的失重量都随之增加,而腐蚀速率却随之下降。在550 ℃下腐蚀1000 h后347H不锈钢和316L不锈钢的腐蚀速率分别为0.0313、0.04439 mm/a。在相同的腐蚀时间下,347H不锈钢表现出更优的耐腐蚀性。

Abstract

In order to investigate the high-temperature corrosion characteristics of a new type of low melting point ternary mixed nitrate, this paper adopts the weight loss method to study the static corrosion behavior of 347H and 316L stainless steel in ternary nitrate at two temperatures of 500 ℃ and 550 ℃. The results show that with the increase of corrosion temperature, the corrosion rate of 347H and 316L stainless steel increases; At the same temperature, as the soaking time increases, the weight loss of 347H and 316 L stainless steel increases, while the corrosion rate decreases. The corrosion rates of 347H stainless steel and 316L stainless steel after 1000 hours of corrosion at 550 ℃ are 0.0313 mm/a and 0.04439 mm/a, respectively. Under the same corrosion time, 347H stainless steel exhibits better corrosion resistance.

关键词

太阳能热发电 / 熔盐 / 硝酸盐 / 腐蚀 / 腐蚀速率 / 低熔点 / 不锈钢

Key words

solar thermal power generation / molten salt / nitrate / corrosion / corrosion rate / low-melting / stainless steel

引用本文

导出引用
韩昕龙, 张春琳, 鹿院卫, 高祺, 王元媛, 吴玉庭. 新型低熔点三元混合硝酸盐高温腐蚀行为研究[J]. 太阳能学报. 2025, 46(8): 309-314 https://doi.org/10.19912/j.0254-0096.tynxb.2024-0500
Han Xinlong, Zhang Chunlin, Lu Yuanwei, Gao Qi, Wang Yuanyuan, Wu Yuting. RESEARCH ON HIGH TEMPERATURE CORROSION BEHAVIOR OF NOVEL LOW MELTING POINT TERNARY MIXED NITRATES[J]. Acta Energiae Solaris Sinica. 2025, 46(8): 309-314 https://doi.org/10.19912/j.0254-0096.tynxb.2024-0500
中图分类号: TK519   

参考文献

[1] 何李丽, 张恒. “双碳” 目标下我国能源转型路径[J]. 上海节能, 2023(9): 1285-1294.
HE L L, ZHANG H.China’s energy transformation path under “double carbon” goal[J]. Shanghai energy saving, 2023(9): 1285-1294.
[2] 刘文彬. 新能源将在国家新型能源体系建设中发挥关键作用[J]. 水电与新能源, 2023, 37(12): 75-78.
LIU W B.New energy resources: key roles in the construction of Chinese national new energy system[J]. Hydropower and new energy, 2023, 37(12): 75-78.
[3] SANG L X, CAI M, REN N, et al.Improving the thermal properties of ternary carbonates for concentrating solar power through simple chemical modifications by adding sodium hydroxide and nitrate[J]. Solar energy materials and solar cells, 2014, 124: 61-66.
[4] 张恩耀, 崔珊, 周鹏, 等. 太阳能热发电高温熔盐腐蚀机理及其影响因素[J]. 化工科技, 2021, 29(1): 71-76.
ZHANG E Y, CUI S, ZHOU P, et al.Corrosion mechanism and influence factors of high temperature molten salt[J]. Science & technology in chemical industry, 2021, 29(1): 71-76.
[5] KEARNEY D, KELLY B, HERRMANN U, et al.Engineering aspects of a molten salt heat transfer fluid in a trough solar field[J]. Energy, 2004, 29(5/6): 861-870.
[6] 王金龙, 鹿院卫, 吴玉庭, 等. 太阳能热发电用熔盐储热材料金属相容性研究[J]. 太阳能学报, 2024, 45(4): 540-545.
WANG J L, LU Y W, WU Y T, et al.Research on metal compatibility of molten salt thermal storage materials for solar thermal power generation[J]. Acta energiae solaris sinica, 2024, 45(4): 540-545.
[7] 李洪川, 李生云, 薛伟伟, 等. 347不锈钢在硝酸熔盐中的腐蚀行为研究[J]. 腐蚀科学与防护技术, 2019, 31(3): 315-319.
LI H C, LI S Y, XUE W W, et al.Corrosion behavior of 347 stainless steel in molten nitrate salts[J]. Corrosion science and protection technology, 2019, 31(3): 315-319.
[8] GOMES A, NAVAS M, URANGA N, et al.High-temperature corrosion performance of austenitic stainless steels type AISI 316L and AISI 321H, in molten solar salt[J]. Solar energy, 2019, 177: 408-419.
[9] FERNÁNDEZ A G, GALLEGUILLOS H, FUENTEALBA E, et al. Corrosion of stainless steels and low-Cr steel in molten Ca(NO3)2-NaNO3-KNO3 eutectic salt for direct energy storage in CSP plants[J]. Solar energy materials and solar cells, 2015, 141: 7-13.
[10] GROSU Y, BONDARCHUK O, FAIK A.The effect of humidity, impurities and initial state on the corrosion of carbon and stainless steels in molten HitecXL salt for CSP application[J]. Solar energy materials and solar cells, 2018, 174: 34-41.
[11] ZHOU C Z, LUO S, SUN Y H, et al.Corrosion behavior of 304 stainless steel in molten nitrate salt at different temperatures[J]. Materials and mechanical engineering, 2019, 43(5): 68-70, 78.
[12] BRASHAW R W, CLIFT W M, Effect of chloride content of molten nitrate salt on corrosion of A516 carbon steel[R]. Albuquerque, Livermore: Sandia National Laboratories, 2010, 12-14
[13] ZHANG X M, ZHANG C C, WU Y T, et al.Experimental research of high temperature dynamic corrosion characteristic of stainless steels in nitrate eutectic molten salt[J]. Solar energy, 2020, 209: 618-627.
[14] 高祺, 鹿院卫, 于强, 等. 杂质氯离子对新型四元硝酸盐腐蚀性的影响[J]. 太阳能学报, 2022, 43(12): 119-123.
GAO Q, LU Y W, YU Q, et al.Influences of impurity chloride ion on corrosion of new quaternary nitrate[J]. Acta energiae solaris sinica, 2022, 43(12): 119-123.
[15] GAO Q, LU Y W, YU Q, et al.High-temperature corrosion behavior of austenitic stainless steel in quaternary nitrate molten salt nanofluids for concentrated solar power[J]. Solar energy materials and solar cells, 2022, 245: 111851.
[16] 赵春. Ca2Fe2O5粉体的制备及表征[D]. 西安: 陕西科技大学, 2012.
ZHAO C.Sythesis and characterization of Ca2Fe2O5 Powders[D]. Xi’an: Shaanxi University of Science & Technology, 2012.
[17] MA L N, ZHANG C C, WU Y T, et al.Comparative review of different influence factors on molten salt corrosion characteristics for thermal energy storage[J]. Solar energy materials and solar cells, 2022, 235: 111485.
[18] 周嘏玥. 316不锈钢在硝酸嫁盐中的腐蚀行为研究[D]. 西安: 西安科技大学, 2017.
ZHOU G Y.Study on the corrosion behaviors of 316 stainless steel in mixtures of molten nitric salt[D]. Xi’an: Xi’an University of Science and Technology, 2017.

基金

国家重点研发计划(2022YFB4202402); 中能建数字科技集团有限公司科技项目(CEECSK-2022-KJ01)

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