甲烷与太阳能互补利用零碳排放制氢系统

马文静; 韩巍; 宋新阳; 刘启斌

doi:10.19912/j.0254-0096.tynxb.2024-1252

太阳能学报 ›› 2025, Vol. 46 ›› Issue (11) : 500-508. DOI: 10.19912/j.0254-0096.tynxb.2024-1252

甲烷与太阳能互补利用零碳排放制氢系统

马文静^1,2, 韩巍^2,3, 宋新阳^2,3, 刘启斌^2,3

作者信息 +

HYDROGEN GENERATION SYSTEM WITH ZERO CARBON DIOXIDE EMISSIONS BASED ON COMPLEMENTARY UTILIZATION OF METHANE AND SOLAR ENERGY

Ma Wenjing^1,2, Han Wei^2,3, Song Xinyang^2,3, Liu Qibin^2,3

Author information +

文章历史 +

摘要

为实现高效低碳制氢,提出一种甲烷与太阳能互补利用的零碳排放制氢系统。该系统将一段式甲烷重整解耦为两段式甲烷重整：部分高温烟气作为反应物引入预重整器,预重整反应热由太阳能提供;重整反应热由驰放气与电解池排放的氧气燃烧提供。剩余烟气预热完待电解的水后直接进行冷凝并分离CO₂。对新系统和参比系统进行能量和㶲平衡分析,结果表明新系统能量和㶲效率提升至42.88%和39.21%,与参比系统相比分别提高了4.77和4.53个百分点。采用图像㶲分析方法揭示系统性能提升的主要原因：对太阳能进行热化学和电化学综合利用,不仅提高了太阳能利用效率,还取消了高能耗CO₂分离装置,㶲效率共提高4.23个百分点;两段式甲烷和烟气重整减少燃烧过程中将高品位甲烷化学能转化为低品位热能,同时也减少了换热过程的㶲损失,㶲效率共提高2.02个百分点。

Abstract

To achieve efficient and low-carbon hydrogen generation, a zero carbon emission hydrogen production system combining methane and solar energy is proposed. The system decouples one-stage methane reforming into two-stage methane reforming： a portion of high-temperature flue gas is introduced into the pre-reforming reactor as reactants, and the reaction heat is provided by solar energy; The reaction heat during the reforming process is providedby combusting purge gas with oxygen from the electrolytic cell. Another part of the flue gas is directly condensed and separated carbon dioxide after preheating the water to be electrolyzed. Energy and exergy balance analyses are conducted on the proposed and reference systems. The results demonstrate that the energy and exergy efficiencies of the proposed system are improved to 42.88% and 39.21%, respectively, by 4.77 and 4.53 percentage points compared to the reference system. Using the exergy utilization diagram （EUD） reveals the main reasons for improved system performance. Comprehensive utilization of solar energy through thermochemistry and electrochemistry. This not only increases the efficiency of solar energy utilization, but also eliminates high-energy consumption carbon dioxide separation devices, resulting in a total increase of 4.23 percentage points in exergy efficiency. The two-stage methane with flue gas reforming process reduces the exergy destruction of high-grade methane chemical energy into low-grade thermal energy during combustion, as well as the heat loss in the heat exchange process, resulting in a total increase of 2.02 percentage points in exergy efficiency.

导出引用

马文静, 韩巍, 宋新阳, 刘启斌. 甲烷与太阳能互补利用零碳排放制氢系统[J]. 太阳能学报. 2025, 46(11): 500-508 https://doi.org/10.19912/j.0254-0096.tynxb.2024-1252

Ma Wenjing, Han Wei, Song Xinyang, Liu Qibin. HYDROGEN GENERATION SYSTEM WITH ZERO CARBON DIOXIDE EMISSIONS BASED ON COMPLEMENTARY UTILIZATION OF METHANE AND SOLAR ENERGY[J]. Acta Energiae Solaris Sinica. 2025, 46(11): 500-508 https://doi.org/10.19912/j.0254-0096.tynxb.2024-1252

中图分类号： TK123

参考文献

[1] 刘贵洲, 窦立荣, 黄永章, 等. 氢能利用的瓶颈分析与前景展望[J]. 天然气与石油, 2021, 39(3): 1-9.
LIU G Z, DOU L R, HUANG Y Z, et al.Analysis on hydrogen energy utilization bottlenecks and future prospect[J]. Natural gas and oil, 2021, 39(3): 1-9.
[2] RAO V T, SEKHAR Y R, PANDEY A K, et al.Thermal analysis of hybrid photovoltaic-thermal water collector modified with latent heat thermal energy storage and two side serpentine absorber design[J]. Journal of energy storage, 2022, 56: 105968.
[3] 张盛, 郑津洋, 戴剑锋, 等. 可再生能源大规模制氢及储氢系统研究进展[J]. 太阳能学报, 2024, 45(1): 457-465.
ZHANG S, ZHENG J Y, DAI J F, et al.Research progress on renewable energy system coupled with large-scale hydrogen production and storage[J]. Acta energiae solaris sinica, 2024, 45(1): 457-465.
[4] ABDIN Z, WEBB C J, GRAY E M.Modelling and simulation of a proton exchange membrane (PEM) electrolyser cell[J]. International journal of hydrogen energy, 2015, 40(39): 13243-13257.
[5] NAVAS-ANGUITA Z, GARCÍA-GUSANO D, DUFOUR J, et al. Revisiting the role of steam methane reforming with CO₂ capture and storage for long-term hydrogen production[J]. The science of the total environment, 2021, 771: 145432.
[6] PRUVOST F, CLOETE S, ARNAIZ DEL POZO C, et al. Blue, green, and turquoise pathways for minimizing hydrogen production costs from steam methane reforming with CO₂ capture[J]. Energy conversion and management, 2022, 274: 116458.
[7] SHEU E J, MOKHEIMER E M A, GHONIEM A F. A review of solar methane reforming systems[J]. International journal of hydrogen energy, 2015, 40(38): 12929-12955.
[8] 雷宇, 袁熹, 王颖, 等. 基于太阳能的甲烷重整制氢技术研究进展[J]. 太阳能学报, 2022, 43(12): 154-160.
LEI Y, YUAN X, WANG Y, et al.Research progress of hydrogen production from methane reforming based on solar energy[J]. Acta energiae solaris sinica, 2022, 43(12): 154-160.
[9] 李勇霞, 段立强, 潘盼, 等. 基于太阳能热驱动甲烷重整制氢的燃料电池发电系统性能研究[J]. 太阳能学报, 2022, 43(9): 131-138.
LI Y X, DUAN L Q, PAN P, et al.Performance research of fuel cell power generation system based on solar thermal driven methane reforming for hydrogen production[J]. Acta energiae solaris sinica, 2022, 43(9): 131-138.
[10] GUO K, LIU M K, WANG B, et al.Hydrogen production and solar energy storage with thermo-electrochemically enhanced steam methane reforming[J]. Science bulletin, 2024, 69(8): 1109-1121.
[11] DONG H, FANG J, YAN X Y, et al.Experimental investigation of solar hydrogen production via photo-thermal driven steam methane reforming[J]. Applied energy, 2024, 368: 123532.
[12] 王秋实, 蒋潇甫, 段立强, 等. 高温太阳能热化学与甲烷互补的SOFC-GT-KC复合动力系统研究[J]. 太阳能学报, 2023, 44(10): 218-228.
WANG Q S, JIANG X F, DUAN L Q, et al.Study on SOFC-GT-KC hybrid power system with high temperature solar thermochemistry and methane complementary[J]. Acta energiae solaris sinica, 2023, 44(10): 218-228.
[13] TSUDA Y, HIRANO T, ECHIGO M.Effect of metal addition to Ni/CeO₂ catalyst on the steam reforming reaction of methane[J]. International journal of hydrogen energy, 2024, 49: 937-948.
[14] ZENG W Q, LI L, SONG M X, et al.The effect of different atmosphere treatments on the performance of Ni/Nb-Al2O3 catalysts for methane steam reforming[J]. International journal of hydrogen energy, 2023, 48(16): 6358-6369.
[15] 王彬, 郭轲, 邵煜, 等. 太阳能甲烷重整制氢研究进展[J]. 洁净煤技术, 2024, 30(9): 1-25.
WANG B, GUO K, SHAO Y, et al.A review on solar methane reforming for hydrogen production[J]. Clean coal technology, 2024, 30(9): 1-25.
[16] HE S, LI S, GAO L.Proposal and energy saving analysis of novel methanol-electricity polygeneration system based on staged coal gasification method[J]. Energy conversion and management, 2021, 233: 113931.
[17] WANG D L, MENG W L, ZHOU H R, et al.Green hydrogen coupling with CO₂ utilization of coal-to-methanol for high methanol productivity and low CO₂ emission[J]. Energy, 2021, 231: 120970.
[18] ZHAO Y J, LIU Q, DUAN Y Y, et al.A multi-dimensional feasibility analysis of coal to methanol assisted by green hydrogen from a life cycle viewpoint[J]. Energy conversion and management, 2022, 268: 115992.
[19] XIN Y, XING X L, LI X, et al.A biomass-solar hybrid gasification system by solar pyrolysis and PV-solid oxide electrolysis cell for sustainable fuel production[J]. Applied energy, 2024, 356: 122419.
[20] 徐钢, 张钟, 吴志聪, 等. 基于绿氢和生物质富氧燃烧技术的零碳甲醇合成系统[J]. 动力工程学报, 2022, 42(10): 925-932.
XU G, ZHANG Z, WU Z C, et al.Zero carbon methanol synthesis system based on green hydrogen and biomass oxygen enriched combustion technology[J]. Journal of Chinese Society of Power Engineering, 2022, 42(10): 925-932.
[21] YUN S, LEE J, CHO H, et al.Oxy-fuel combustion-based blue hydrogen production with the integration of water electrolysis[J]. Energy conversion and management, 2023, 291: 117275.
[22] SU B S, WANG Y L, XU Z L, et al.Novel ways for hydrogen production based on methane steam and dry reforming integrated with carbon capture[J]. Energy conversion and management, 2022, 270: 116199.
[23] NIKOO M K, AMIN N A S. Thermodynamic analysis of carbon dioxide reforming of methane in view of solid carbon formation[J]. Fuel processing technology, 2011, 92(3): 678-691.
[24] LI D, DUAN L Q.Techno-economic analysis of a new thermal storage operation strategy for a solar aided liquid air energy storage system[J]. Journal of energy storage, 2024, 78: 110029.
[25] WANG Q S, DUAN L Q, LU Z Y, et al.Thermodynamic performance coMParison of SOFC-MGT-CCHP systems coupled with two different solar methane steam reforming processes[J]. International journal of hydrogen energy, 2023, 48(71): 27473-27491.
[26] CAO Y L, ZHANG H, LIU X Y, et al.A strategy of mid-temperature natural gas based chemical looping reforming for hydrogen production[J]. International journal of hydrogen energy, 2022, 47(24): 12052-12066.
[27] WANG H S, LI W J, LIU T, et al.Thermodynamic analysis and optimization of photovoltaic/thermal hybrid hydrogen generation system based on complementary combination of photovoltaic cells and proton exchange membrane electrolyzer[J]. Energy conversion and management, 2019, 183: 97-108.
[28] AOUALI F Z, BECHERIF M, RAMADAN H S, et al.Analytical modelling and experimental validation of proton exchange membrane electrolyser for hydrogen production[J]. International journal of hydrogen energy, 2017, 42(2): 1366-1374.