温度对燃料电池质子交换膜应力松弛性能的影响研究

刘蕾; 刘士华; 庞林家; 耿铁; 郭永刚; 王心超

doi:10.19912/j.0254-0096.tynxb.2024-1631

PDF(1148 KB)

太阳能学报 ›› 2026, Vol. 47 ›› Issue (1) : 35-41. DOI: 10.19912/j.0254-0096.tynxb.2024-1631

温度对燃料电池质子交换膜应力松弛性能的影响研究

刘蕾¹, 刘士华¹, 庞林家¹, 耿铁^1,2, 郭永刚¹, 王心超¹

作者信息 +

STUDY ON INFLUENCE OF TEMPERATURE ON STRESS RELAXATION PROPERTIES OF PROTON EXCHANGE MEMBRANE IN FUEL CELLS

Liu Lei¹, Liu Shihua¹, Pang Linjia¹, Geng Tie^1,2, Guo Yonggang¹, Wang Xinchao¹

Author information +

文章历史 +

摘要

以燃料电池中质子交换膜为研究对象,建立7参数Maxwell模型,利用该模型得到不同温度下质子交换膜初始状态和稳定状态下松弛特性的拟合结果。研究结果显示,7参数Maxwell模型与实验结果的拟合误差较小,且能有效描述膜应力变化趋势,证明其高精度与可靠性。该模型的建立有助于深入理解膜在实际运行中的动态响应和稳定性,进而优化膜材料的设计和选择,延长燃料电池系统的使用寿命。

Abstract

A Maxwell model with 7 parameters is established using the proton exchange membranes in fuel cells as the research object. The model is used to fit the relaxation modulus of the membrane in both its initial and stable states across different temperature levels. The research results indicate that the fitting error between this model and experimental results is minimal. The model can effectively capture the membrane’s relaxation modulus changes. This demonstrates its high accuracy and reliability. The model contributes to a deeper understanding of the dynamic response and stability of the membrane in operation, thereby optimizing the design and selection of membrane materials and extending the lifespan of fuel cell systems.

导出引用

刘蕾, 刘士华, 庞林家, 耿铁, 郭永刚, 王心超. 温度对燃料电池质子交换膜应力松弛性能的影响研究[J]. 太阳能学报. 2026, 47(1): 35-41 https://doi.org/10.19912/j.0254-0096.tynxb.2024-1631

Liu Lei, Liu Shihua, Pang Linjia, Geng Tie, Guo Yonggang, Wang Xinchao. STUDY ON INFLUENCE OF TEMPERATURE ON STRESS RELAXATION PROPERTIES OF PROTON EXCHANGE MEMBRANE IN FUEL CELLS[J]. Acta Energiae Solaris Sinica. 2026, 47(1): 35-41 https://doi.org/10.19912/j.0254-0096.tynxb.2024-1631

中图分类号： TK91

参考文献

[1] 赵金国, 郭恒. 氢燃料电池氢气利用率提升策略研究[J]. 太阳能学报, 2022, 43(8): 510-516.ZHAO J G, GUO H. Research on hydrogen utilization rate enhancement strategy of hydrogen fuel cell[J]. Acta energiae solaris sinica, 2022, 43(8): 510-516.
[2] 汪树军, 赵永丰. 氢能发电技术的研究(Ⅲ): 离子交换膜对离子膜颜料电池放电性能的影响[J]. 太阳能学报, 2001, 22(2): 214-218.WANG S J, ZHAO Y F. Study on the technology of the hydrogen energy to generate electricity(ⅲ): the effect of the ion exchange membrane on the discharge property of the ion exchange membrane fuel cells[J]. Acta energiae solaris sinica, 2001, 22(2): 214-218.
[3] 纪合超, 陈涛, 刘士华, 等. 质子交换膜燃料电池温度监控系统的设计与开发[J]. 太阳能学报, 2020, 41(11): 375-380.JI H C, CHEN T, LIU S H, et al. Design and development of temperature monitoring system for proton exchange membrane fuel cells[J]. Acta energiae solaris sinica, 2020, 41(11): 375-380.
[4] 徐玉蓉, 罗仁宏, 崔嵘, 等. 应用于氢燃料电池的均温板传热性能多因素优化研究[J]. 太阳能学报, 2024, 45(6): 86-91.XU Y R, LUO R H, CUI R, et al. Multi-factor optimization of heat transfer performance of temperature equalizing plate applied to hydrogen fuel cell[J]. Acta energiae solaris sinica, 2024, 45(6): 86-91.
[5] 柯育智, 袁伟, 张少鹏, 等. 燃料电池质子交换膜表面微结构热压工艺热力耦合特性研究[J]. 机械工程学报, 2024, 60(14): 317-328.KE Y Z, YUAN W, ZHANG S P, et al. Study on thermo-mechanical coupling characteristics of hot pressing on surface microstructures of proton exchange membrane for fuel cells[J]. Journal of mechanical engineering, 2024, 60(14): 317-328.
[6] 王燕康, 谈金祝. 在模拟PEM燃料电池环境下质子交换膜化学损伤研究[J]. 太阳能学报, 2021, 42(9): 434-438.WANG Y K, TAN J Z. Study on chemical degradation of proton exchange membrane in simulated pem fuel cell environments[J]. Acta energiae solaris sinica, 2021, 42(9): 434-438.
[7] 叶东浩, 李永静, 汪广进, 等. PEM燃料电池膜电极边框材料对膜干湿应力影响研究[J]. 武汉理工大学学报, 2012, 34(10): 1-4.YE D H, LI Y J, WANG G J, et al. Stress effect of membrane electrode frame on the membrane dry-wet cycling in PEM fuel cell[J]. Journal of Wuhan University of Technology, 2012, 34(10): 1-4.
[8] 杨卫战, 谈金祝, 刘嘉然, 等. 模拟PEM燃料电池环境下质子交换膜损伤研究[J]. 太阳能学报, 2022, 43(9): 493-498.YANG W Z, TAN J Z, LIU J R, et al. Study on degradation of proton exchange membrane in simulated PEM fuel cell environments[J]. Acta energiae solaris sinica, 2022, 43(9): 493-498.
[9] TANG Y L, KUSOGLU A, KARLSSON A M, et al.Mechanical properties of a reinforced composite polymer electrolyte membrane and its simulated performance in PEM fuel cells[J]. Journal of power sources, 2008, 175(2): 817-825.
[10] SHI S W, CHEN G, WANG Z F, et al.Mechanical properties of Nafion 212 proton exchange membrane subjected to hygrothermal aging[J]. Journal of power sources, 2013, 238: 318-323.
[11] KUSOGLU A, KARLSSON A M, SANTARE M H, et al.Mechanical response of fuel cell membranes subjected to a hygro-thermal cycle[J]. Journal of power sources, 2006, 161(2): 987-996.
[12] SOLASI R, ZOU Y, HUANG X Y, et al.On mechanical behavior and in-plane modeling of constrained PEM fuel cell membranes subjected to hydration and temperature cycles[J]. Journal of power sources, 2007, 167(2): 366-377.
[13] LU Z W, LUGO M, SANTARE M H, et al.An experimental investigation of strain rate, temperature and humidity effects on the mechanical behavior of a perfluorosulfonic acid membrane[J]. Journal of power sources, 2012, 214: 130-136.
[14] KUSOGLU A, TANG Y L, LUGO M, et al.Constitutive response and mechanical properties of PFSA membranes in liquid water[J]. Journal of power sources, 2010, 195(2): 483-492.
[15] SATTERFIELD M B, BENZIGER J B.Viscoelastic properties of Nafion at elevated temperature and humidity[J]. Journal of polymer science part B: polymer physics, 2009, 47(1): 11-24.
[16] YOON W, HUANG X Y, SOLASI R.Experimental validation of a constitutive model for ionomer membrane in polymer electrolyte membrane fuel cell (PEMFC)[C]//Experimental Mechanics on Emerging Energy Systems and Materials, Volume 5. New York, NY: Springer, 2011: 33-40.
[17] MAY J A, ELLIS M W, DILLARD D A, et al.Development and validation of a uniaxial nonlinear viscoelastic viscoplastic stress model for a fuel cell membrane[J]. Journal of fuel cell science and technology, 2015, 12(6): 061011.
[18] LIU D, HICKNER M A, CASE S W, et al.Relaxation of proton conductivity and stress in proton exchange membranes under strain[J]. Journal of engineering materials and technology, 2006, 128(4): 503-508.
[19] LAI Y H, MITTELSTEADT C K, GITTLEMAN C S, et al.Viscoelastic stress analysis of constrained proton exchange membranes under humidity cycling[J]. Journal of fuel cell science and technology, 2009, 6(2): 021002.
[20] HU Y Q, DING S H, PAN M X, et al.Temperature-dependent mechanical performance of Nafion® 212 proton exchange membrane under uniaxial and biaxial loading[J]. Journal of applied polymer science, 2023, 140(33): e54271.