以隧穿氧化层钝化接触(TOPCon)太阳电池为研究对象,通过实验研究的方法,对TOPCon太阳电池的亚稳态效应及紫外(UV)辐照影响进行实验验证。研究结果表明:TOPCon太阳电池存在亚稳态效应,紫外辐照对太阳电池的影响存在先上升后下降的变化。在紫外预处理约1 s后电池平均光电转换效率(PCE)提升0.07%,开路电压(Voc)提升0.89 mV,填充因子(FF)提升0.15%,而长时间的辐照则引起太阳电池钝化效果的恶化,最终降低PCE。该文首次发现,对电池进行短时间紫外辐照处理可以提升其效率,为开发高效低成本TOPCon太阳电池奠定了重要基础。
Abstract
This study investigates the metastable effect and ultraviolet (UV) irradiation influence on tunnel oxide passivated contact (TOPCon) solar cells through experimental methods. The results demonstrate that TOPCon solar cells exhibit a metastable effect, and the impact of UV irradiation on the cells follows a trend of initial enhancement followed by degradation. After approximately 1 s of UV pretreatment, the average power conversion efficiency (PCE) of the cells increases by 0.07%, accompanied by a 0.89 mV improvement in open-circuit voltage (Voc) and a 0.15% rise in fill factor (FF). However, prolonged UV irradiation degrades the passivation effectiveness, ultimately reducing the PCE. For the first time, this paper finds that short-time UV irradiation treatment on the cell can improve its efficiency, which lays an important foundation for the development of high-efficiency and low-cost TOPCon solar cells.
关键词
太阳电池 /
亚稳态效应 /
紫外辐照 /
光电转换效率 /
高效低成本 /
TOPCon
Key words
solar cells /
metastable effect /
UV irradiation /
power conversion efficiency /
high-efficiency and low-cost /
TOPCon
{{custom_sec.title}}
{{custom_sec.title}}
{{custom_sec.content}}
参考文献
[1] Long W, Yin S, Peng F G, et al.On the limiting efficiency for silicon heterojunction solar cells[J]. Solar Energy Materials and Solar Cells, 2021, 231: 111291.
[2] Green M A, Dunlop E D, Yoshita M, et al.Solar cell efficiency tables(Version 64)[J]. Progress in Photovoltaics: Research and Applications, 2024, 32(7): 425-441.
[3] Ding Z T, Truong T N, Nguyen H T, et al.Boron spin-on doping for poly-Si/SiOx passivating contacts[J]. ACS Applied Energy Materials, 2021, 4(5): 4993-4999.
[4] Yu J, Chen Y, He J L, et al.Enhancing poly-Si contact through a highly conductive and ultra-thin TiN layer for high-efficiency passivating contact silicon solar cells[J]. Solar Energy Materials and Solar Cells, 2023, 260: 112491.
[5] 白宇, 何佳龙, 李君君, 等. 光电性能可调的TiN薄膜及在TOPCon太阳电池的应用[J]. 太阳能学报, 2023, 44(9): 72-77.
Bai Y, He J L, Li J J, et al.TiN thin film with adjustable photoelectric performance and its application in TOPCon solar cell[J]. Acta Energiae Solaris Sinica, 2023, 44(9): 72-77.
[6] 叶浩然, 何佳龙, 陈杨, 等. TOPCon太阳电池电子选择性接触研究[J]. 太阳能学报, 2024, 45(2): 475-479.
Ye H R, He J L, Chen Y, et al.Research on electron selective contact of TOPCon solar cells[J]. Acta Energiae Solaris Sinica, 2024, 45(2): 475-479.
[7] 黄嘉斌, 赵增超, 李明, 等. 管式PECVD制备原位掺杂多晶硅的性能研究[J]. 太阳能学报, 2024, 45(6): 334-340.
Huang J B, Zhao Z C, Li M, et al.Study on performance of in-situ doped polysilicon prepared by tube PECVD[J]. Acta Energiae Solaris Sinica, 2024, 45(6): 334-340.
[8] Thome F T, Meßmer P, Mack S, et al.UV-induced degradation of industrial PERC, TOPCon, and HJT solar cells: the next big reliability challenge?[J]. Solar RRL, 2024, 8(23): 2400628.
[9] 任勇, 陈德爽, 葛剑杰, 等. TOPCon太阳电池的UV辐照衰减特性及抗UV辐照方式研究[J]. 太阳能, 2024(11): 43-54.
Ren Y, Chen D S, Ge J J, et al.Research on UV irradiation attenuation characteristics and UV irradiation resistance methods of TOPCon solar cells[J]. Solar Energy, 2024(11): 43-54.
[10] Gebhardt P, Kräling U, Fokuhl E, et al.Reliability of commercial TOPCon PV modules: an extensive comparative study[J]. Progress in Photovoltaics: Research and Applications, 2025, 33(12): 1378-1386.
[11] Sinha A, Qian J D, Moffitt S L, et al.UV-induced degradation of high-efficiency silicon PV modules with different cell architectures[J]. Progress in Photovoltaics: Research and Applications, 2023, 31(1): 36-51.
[12] Sinha A, Jaubert J N, Karin T.UV-induced degradation susceptibility of industrial N-type silicon high-efficiency PV modules[C]//2024 IEEE 52nd Photovoltaic Specialist Conference (PVSC). Seattle, WA, USA, 2024: 1745-1747.
[13] Weiss T P, Ramírez O, Paetel S, et al.Metastable defects decrease the fill factor of solar cells[J]. Physical Review Applied, 2023, 19(2): 024052.
[14] 曾庆国. n型晶体硅太阳电池后处理增效研究[D]. 南昌: 南昌大学, 2024.
Zeng Q G.A study of the enhancement of n-type crystalline silicon solar cells by post-treatment[D]. Nanchang: Nanchang University, 2024.
[15] 于雷飞. TOPCon太阳电池氢钝化技术的研究[D]. 无锡: 江南大学, 2024.
Yu L F.Study of hydrogenation for TOPCon solar cells[D]. Wuxi: Jiangnan University, 2024.
[16] Gruenbaum P E, Sinton R A, Swanson R M.Light-induced degradation at the silicon/silicon dioxide interface[J]. Applied Physics Letters, 1988, 52(17): 1407-1409.
[17] Gruenbaum P E, Sinton R A, Swanson R M.Stability problems in point contact solar cells[C]//Conference Record of the Twentieth IEEE Photovoltaic Specialists Conference. Las Vegas, NV, USA, 1988: 423-428.
[18] Gruenbaum P E, Gan J Y, King R R, et al.Stable passivations for high-efficiency silicon solar cells[C]//IEEE Conference on Photovoltaic Specialists. Kissimmee, FL, USA, 1990: 317-322.
[19] Kamioka T, Takai D, Tachibana T, et al.Plasma damage effect on ultraviolet-induced degradation of PECVD SiNx: H passivation[C]//2015 IEEE 42nd Photovoltaic Specialist Conference (PVSC). New Orleans, LA, USA, 2015: 1-3.
[20] Mayne A J, Riedel D, Comtet G, et al.Atomic-scale studies of hydrogenated semiconductor surfaces[J]. Progress in Surface Science, 2006, 81(1): 1-51.
[21] Ye H R, Huang S L, Qian C, et al.Short wavelength photons destroying Si-H bonds and its influence on high-efficiency silicon solar cells and modules[J]. Solar RRL, 2023, 7(15): 2370153.
基金
四川省科学技术厅区域创新合作项目(2025YFHZ0332); 宜宾市引进高层次人才项目(2024YG05)