STUDY ON FATIGUE DAMAGE OF GASKET MATERIAL IN SIMULATED PEM FUEL CELL ENVIRONMENTS

Li Yang, Tan Jinzhu, Wang Zhiqiang, Lu Yan, Wang Chao

Acta Energiae Solaris Sinica ›› 2022, Vol. 43 ›› Issue (5) : 433-437.

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Acta Energiae Solaris Sinica ›› 2022, Vol. 43 ›› Issue (5) : 433-437. DOI: 10.19912/j.0254-0096.tynxb.2020-0921

STUDY ON FATIGUE DAMAGE OF GASKET MATERIAL IN SIMULATED PEM FUEL CELL ENVIRONMENTS

  • Li Yang, Tan Jinzhu, Wang Zhiqiang, Lu Yan, Wang Chao
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Abstract

The elastomeric gasket is one of the key components in the proton exchange membrane (PEM) fuel cell. During the long-term operation of the PEM fuel cell, the damage of the gasket material is critical to the durability of the PEM fuel cell. In this paper, the silicone rubber elastomeric material, which is widely used for PEM fuel cells, was selected and studied. The fatigue damage was investigated for the gasket material exposed to the simulated PEM fuel cell environments in this work. Two solutions were selected to simulate the PEM fuel cell environment, one was close to the real PEM fuel cell environment, namely regular solution (RS), and the other was the accelerated durability test (ADT) solution for accelerated damage test. Compression fatigue tests and flexural fatigue tests were performed to study the fatigue damage behavior of the gasket material for exposure to two solutions. The result of compression fatigue tests shows that the PEM fuel cell simulation environment and aging time have an important influence on the compression fatigue temperature rise of the sample. The fatigue temperature rises of the sample exposed to the ADT solution was higher than that to the RS solution. With the aging time increased, the fatigue temperature rises of the sample increased, and the fatigue damage intensified. The result of flexural fatigue tests shows that the PEM fuel cell simulation environment and aging time have a significant impact on the fatigue life of the sample. The fatigue life of the sample exposed to the ADT solution is shorter than that to the RS solution; With the aging time increased, the fatigue life of the sample decreased.

Key words

proton exchange membrane / fuel cells / gaskets / fatigue damage / aging

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Li Yang, Tan Jinzhu, Wang Zhiqiang, Lu Yan, Wang Chao. STUDY ON FATIGUE DAMAGE OF GASKET MATERIAL IN SIMULATED PEM FUEL CELL ENVIRONMENTS[J]. Acta Energiae Solaris Sinica. 2022, 43(5): 433-437 https://doi.org/10.19912/j.0254-0096.tynxb.2020-0921

References

[1] LIANG P, QIU D K, PENG L F, et al.Structure failure of the sealing in the assembly process for proton exchange membrane fuel cells[J]. International journal of hydrogen energy, 2017, 42(15): 10217-10227.
[2] HOU Y P, HAO D, SHEN J P, et al.Effect of strengthened road vibration on performance degradation of PEM fuel cell stack[J]. International journal of hydrogen energy, 2016, 41(9): 5123-5134.
[3] WU F, CHEN B, YAN Y Z, et al.Degradation of silicone rubbers as sealing materials for proton exchange membrane fuel cells under temperature cycling[J]. Polymers, 2018, 10(5): 522.
[4] 苏俊杰, 魏雪峰, 冯莺. 屈挠温度和屈挠频率对天然橡胶耐屈挠疲劳性能的影响[J]. 橡胶科技, 2019, 17(3): 136-139.
SU J J, WEI X F, FENG Y.Effect of flexural temperature and flexural frequency on flexural fatigue resistance of natural rubber[J]. Rubber science and technology, 2019, 17(3): 136-139.
[5] BEURROT S, HUNEAU B, VERRON E.In situ SEM study of fatigue crack growth mechanism in carbon black-filled natural rubber[J]. Journal of applied polymer science, 2010, 117(3): 1260-1269.
[6] LI G, TAN J Z, GONG J M.Degradation of the elastomeric gasket material in a simulated and four accelerated proton exchange membrane fuel cell environments[J]. Journal of power sources, 2012, 205: 244-251.
[7] 殷金鹏, 谈金祝, 张武建, 等. 模拟PEM燃料电池环境下垫片材料的机械性能研究[J]. 太阳能学报, 2018, 39(3): 686-691.
YIN J P, TAN J Z, ZHANG W J, et al.Study on mechanical properties of the gasket material in simulated PEM fuel cell environments[J]. Acta energiae solaris sinica, 2018, 39(3): 686-691.
[8] WANG Z Q, TAN J Z, WANG Y K, et al.Chemical and mechanical degradation of silicone rubber under two compression loads in simulated proton-exchange membrane fuel-cell environments[J]. Journal of applied polymer science, 2019, 136(33): 47855.
[9] TAN J Z, CHAO Y J, YANG M, et al.Chemical and mechanical stability of a Silicone gasket material exposed to PEM fuel cell environment[J]. International journal of hydrogen energy, 2011, 36(2): 1846-1852.
[10] GB/T1687.3—2016, 硫化橡胶在屈挠试验中温升和耐疲劳性能的测定[S].
GB/T1687.3—2016,Determination of temperature rise and fatigue resistance of vulcanized rubber in flexural test[S].
[11] GB/T 13934—2006, 硫化橡胶或热塑性橡胶屈挠龟裂和裂口增长的测定[S].
GB/T 13934—2006,Vulcanized or thermoplastic rubber—Determination of flexural cracking and crack growth[S].
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