HYDROGENATION PERFORMANCE OF DIBENZYLTOLUENE CATALYZED BY Ni-RICH La-Ni ALLOYS

Feng Xiaoyang; Jiang Lijun; Li Zhinian; Wu Yuanfang; Ye Jianhua; Wang Qi

doi:10.19912/j.0254-0096.tynxb.2022-0479

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Acta Energiae Solaris Sinica ›› 2022, Vol. 43 ›› Issue (6) : 382-388. DOI: 10.19912/j.0254-0096.tynxb.2022-0479

HYDROGENATION PERFORMANCE OF DIBENZYLTOLUENE CATALYZED BY Ni-RICH La-Ni ALLOYS

Feng Xiaoyang^1,2, Jiang Lijun^1,3, Li Zhinian^1,2, Wu Yuanfang^1,2, Ye Jianhua^1,3, Wang Qi^1,2

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Abstract

La-Ni alloys are prepared by induction melting and ball milling, and Ni-rich La-Ni alloys are further prepared in situ by an acid treatment method. The hydrogenation performance of dibenzyltoluene catalyzed by La-Ni alloys prepared with different conditions is studied. The hydrogenation amount of dibenzyltoluene catalyzed by Ni-rich La-Ni alloys reaches 5.34%（mass concentration） at 280 ℃ for 4 h, and finally reaches the theoretical maximum value after 20 h. The excellent catalytic hydrogenation activity of Ni-rich La-Ni alloys is mainly attributed to the mutual promotion between the efficient catalysis of Ni and the reversible hydrogen absorption and desorption ability of La-Ni alloys.

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hydrogen storage / liquid organic hydrogen carrier / dibenzyltoluene / hydrogenation / catalysts / La-Ni alloys

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Feng Xiaoyang, Jiang Lijun, Li Zhinian, Wu Yuanfang, Ye Jianhua, Wang Qi. HYDROGENATION PERFORMANCE OF DIBENZYLTOLUENE CATALYZED BY Ni-RICH La-Ni ALLOYS[J]. Acta Energiae Solaris Sinica. 2022, 43(6): 382-388 https://doi.org/10.19912/j.0254-0096.tynxb.2022-0479

References

[1] HASSAN I A, RAMADAN H S, SALEH M A, et al.Hydrogen storage technologies for stationary and mobile applications: review, analysis and perspectives[J]. Renewable and sustainable energy reviews, 2021, 149: 111311.
[2] ANDERSSON J, GRÖNKVIST S. Large-scale storage of hydrogen[J]. International journal of hydrogen energy, 2019, 44(23): 11901-11919.
[3] EBERLE U, FELDERHOFF M, SCHUETH F.Chemical and physical solutions for hydrogen storage[J]. Angewandte chemie international edition, 2009, 48(36): 6608-6630.
[4] LANG C G, JIA Y, YAO X D.Recent advances in liquid-phase chemical hydrogen storage[J]. Energy storage materials, 2020, 26: 290-312.
[5] NASEEM M, USMAN M, LEE S.A parametric study of dehydrogenation of various Liquid Organic Hydrogen Carrier(LOHC) materials and its application to methanation process[J]. International journal of hydrogen energy, 2021, 46(5): 4100-4115.
[6] MODISHA P M, OUMA C N M, GARIDZIRAI R, et al. The prospect of hydrogen storage using liquid organic hydrogen carriers[J]. Energy & fuels, 2019, 33(4): 2778-2796.
[7] BRUCKNER N, OBESSER K, BOSMANN A, et al.Evaluation of industrially applied heat-transfer fluids as liquid organic hydrogen carrier systems[J]. ChemSusChem, 2014, 7(1): 229-235.
[8] NIERMANN M, BECKENDORFF A, KALTSCHMITT M, et al.Liquid Organic Hydrogen Carrier (LOHC)-assessment based on chemical and economic properties[J]. International journal of hydrogen energy, 2019, 44(13): 6631-6654.
[9] AAKKO-SAKSA P T, VEHKAMAKI M, KEMELL M, et al. Hydrogen release from liquid organic hydrogen carriers catalysed by platinum on rutile-anatase structured titania[J]. Chemical communications, 2020, 56(11): 1657-1660.
[10] AUER F, BLAUMEISER D, BAUER T, et al.Boosting the activity of hydrogen release from liquid organic hydrogen carrier systems by sulfur-additives to Pt on alumina catalysts[J]. Catalysis science & technology, 2019, 9(13): 3537-3547.
[11] SHI L B, QI S T, QU J F, et al.Integration of hydrogenation and dehydrogenation based on dibenzyltoluene as liquid organic hydrogen energy carrier[J]. International journal of hydrogen energy, 2019, 44(11): 5345-5354.
[12] SISAKOVA K, PODROJKOVA N, ORINAKOVA R, et al.Novel catalysts for dibenzyltoluene as a potential liquid organic hydrogen carrier use—a mini-review[J]. Energy & fuels, 2021, 35(9): 7608-7623.
[13] SHI L B, ZHOU Y M, QI S T, et al.Pt catalysts supported on H₂ and O₂ plasma-treated Al₂O₃ for hydrogenation and dehydrogenation of the liquid organic hydrogen carrier pair dibenzyltoluene and perhydrodibenzyltoluene[J]. ACS catalysis, 2020, 10(18): 10661-10671.
[14] DO G, PREUSTER P, ASLAM R, et al.Hydrogenation of the liquid organic hydrogen carrier compound dibenzyltoluene-reaction pathway determination by ¹H NMR spectroscopy[J]. Reaction chemistry & engineering, 2016, 1(3): 313-320.
[15] WU Y, YU H E, GUO Y R, et al.Promoting hydrogen absorption of liquid organic hydrogen carriers by solid metal hydrides[J]. Journal of materials chemistry A, 2019, 7(28): 16677-16684.
[16] WU Y, YU H E, GUO Y R, et al.A rare earth hydride supported ruthenium catalyst for the hydrogenation of N-heterocycles: boosting the activity via a new hydrogen transfer path and controlling the stereoselectivity[J]. Chemical science, 2019, 10(45): 10459-10465.
[17] WU Y, GUO Y R, YU H E, et al.Nonstoichiometric yttrium hydride-promoted reversible hydrogen storage in a liquid organic hydrogen carrier[J]. CCS chemistry, 2021, 3(3): 974-984.
[18] CUEVAS F, LATROCHE M, HIRSCHER M, et al.Formation and structure of highly over-stoichiometric LaNi₅+_x (x～1) alloys obtained by manifold non-equilibrium methods[J]. Journal of alloys and compounds, 2001, 323: 4-7.
[19] 周增林, 宋月清, 崔舜, 等. 高倍率AB₅型稀土贮氢合金的研究进展[J]. 稀有金属, 2004, 28(2): 408-413.
ZHOU Z L, SONG Y Q, CUI S, et al.Development of rare earth-based AB₅-type hydrogen-storage alloys with high-rate dischargeability[J]. Chinese journal of rare metals, 2004, 28(2): 408-413.
[20] 宋佩维, 马玉韩. 化学计量比对AB₅型贮氢合金相结构及电化学性能的影响[J]. 稀土, 2006, 27(4): 48-52.
SONG P W, MA Y H.Effect of stoichiometric ratio on structure and electrochemical properties of AB₅-type hydrogen storage alloys[J]. Chinese rare metals, 2006, 27(4): 48-52.
[21] ISE T, MURATA T, HIROTA Y, et al.The surface structure and the electrochemical properties of hydrogen-absorbing alloys treated with an HCl aqueous solution[J]. Journal of alloys and compounds, 2000, 307(1-2): 324-332.
[22] YU H E, YANG X, JIANG X J, et al.LaNi_5.5 particles for reversible hydrogen storage in N-ethylcarbazole[J]. Nano energy, 2021, 80: 105476.
[23] LIU W, AGUEY-ZINSOU K F. Synthesis of highly dispersed nanosized LaNi₅ on carbon: revisiting particle size effects on hydrogen storage properties[J]. International journal of hydrogen energy, 2016, 41(32): 14429-14436.
[24] DING Y H, DONG Y, ZHANG H S, et al.A highly adaptable Ni catalyst for liquid organic hydrogen carriers hydrogenation[J]. International journal of hydrogen energy, 2021, 46(53): 27026-27036.
[25] YE T N, LU Y, KOBAYASHI Y, et al.Efficient ammonia synthesis over phase-separated nickel-based intermetallic catalysts[J]. The journal of physical chemistry C, 2020, 124(52): 28589-28595.
[26] ZHONG D, OUYANG L Z, LIU J W, et al.Metallic Ni nanocatalyst in situ formed from LaNi₅H₅ toward efficient CO₂ methanation[J]. International journal of hydrogen energy, 2019, 44(55): 29068-29074.