STUDY ON PREPARATION OF MODIFIED WASTE PAPER PULP BIOCHAR-BASED CATALYST AND ITS CATALYTIC APPLICATION FOR BIODIESEL PRODUCTION

Zhao Dandan; Zhao Wei; Shan Rui; Chen Dezhen; Yuan Haoran; Chen Yong

doi:10.19912/j.0254-0096.tynxb.2022-0722

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Acta Energiae Solaris Sinica ›› 2023, Vol. 44 ›› Issue (9) : 432-439. DOI: 10.19912/j.0254-0096.tynxb.2022-0722

STUDY ON PREPARATION OF MODIFIED WASTE PAPER PULP BIOCHAR-BASED CATALYST AND ITS CATALYTIC APPLICATION FOR BIODIESEL PRODUCTION

Zhao Dandan^1,2, Zhao Wei³, Shan Rui², Chen Dezhen¹, Yuan Haoran^1,2, Chen Yong^1,2

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Abstract

In this paper, pulp & paper sludge biochar is used as a carrier to prepare a solid base catalyst and applied to the preparation of biodiesel. The physicochemical properties of the catalyst were analyzed by thermogravimetric analysis （TGA）, scanning electron microscope & energy dispersive spectrometer （SEM-EDS）, Fourier transform infrared spectroscopy （FTIR）, X-ray diffraction （XRD）, N₂ adsorption/desorption and CO₂-TPD for characterization. The results show that 30K/PPSB-600 has the highest total alkalinity, and it has excellent catalytic activity （maximum biodiesel yield is 98.5%）. In addition, the stability and reusability of the catalyst were also examined. After 8 times of repeated use, the catalyst still has high catalytic activity （biodiesel yield is 80%）. The small amount of catalyst deactivation is mainly due to the loss of K⁺ ions.

Key words

biodiesel / transesterification / sludge / biochar

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Zhao Dandan, Zhao Wei, Shan Rui, Chen Dezhen, Yuan Haoran, Chen Yong. STUDY ON PREPARATION OF MODIFIED WASTE PAPER PULP BIOCHAR-BASED CATALYST AND ITS CATALYTIC APPLICATION FOR BIODIESEL PRODUCTION[J]. Acta Energiae Solaris Sinica. 2023, 44(9): 432-439 https://doi.org/10.19912/j.0254-0096.tynxb.2022-0722

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