EFFECT OF AMMONIUM DIHYDROGEN PHOSPHATE ON PYROLYSIS CHARACTERISTICS OF POPLAR

Chen Meng, Pang Yunji, Wu Meifeng, Chen Yisheng, Wang Li

Acta Energiae Solaris Sinica ›› 2024, Vol. 45 ›› Issue (12) : 444-451.

PDF(1485 KB)
Welcome to visit Acta Energiae Solaris Sinica, Today is
PDF(1485 KB)
Acta Energiae Solaris Sinica ›› 2024, Vol. 45 ›› Issue (12) : 444-451. DOI: 10.19912/j.0254-0096.tynxb.2023-1279

EFFECT OF AMMONIUM DIHYDROGEN PHOSPHATE ON PYROLYSIS CHARACTERISTICS OF POPLAR

  • Chen Meng, Pang Yunji, Wu Meifeng, Chen Yisheng, Wang Li
Author information +
History +

Abstract

To investigate the effect of ammonium dihydrogen phosphate (MAP) on the quality of pyrolysis products of poplar and its derived charcoal, revealing the factors presented by MAP for improving poplar quality and catalytic tar cracking. Select MAP impregnation solutions of different concentrations for in-situ impregnation loading into poplar for low-temperature carbonization and derived carbon pyrolysis experiments. Study the influence of different MAP concentrations on the three-phase yield, biochar calorific value, and energy yield of poplar carbonization. Investigate the catalytic cracking phenomenon of derivative carbon pyrolysis with the addition of MAP compared with the direct pyrolysis of raw materials. The results indicate that low-temperature carbonization combined with the addition of MAP has a synergistic effect on the increase of poplar pyrolysis char and the decrease of tar, When the pyrolysis temperature is 500 ℃, Compared to the absence of derivative carbon, the addition of 1.975% MAP derivative carbon results in a 19.8% decrease in phenolic products and a 5.38% decrease in toluene products in the tar component. This study can provide a basis for the preparation and application of high-quality and relatively clean derived carbons.

Key words

phosphates / poplar wood / phenols / derived carbon / low temperature charring / pyrolysis

Cite this article

Download Citations
Chen Meng, Pang Yunji, Wu Meifeng, Chen Yisheng, Wang Li. EFFECT OF AMMONIUM DIHYDROGEN PHOSPHATE ON PYROLYSIS CHARACTERISTICS OF POPLAR[J]. Acta Energiae Solaris Sinica. 2024, 45(12): 444-451 https://doi.org/10.19912/j.0254-0096.tynxb.2023-1279

References

[1] ZHANG S, SONG Y, SONG Y C, et al.An advanced biomass gasification technology with integrated catalytic hot gas cleaning. Part III: effects of inorganic species in char on the reforming of tars from wood and agricultural wastes[J]. Fuel, 2016, 183: 177-184.
[2] CHEN D Y, CEN K H, CAO X B, et al.Restudy on torrefaction of corn stalk from the point of view of deoxygenation and decarbonization[J]. Journal of analytical and applied pyrolysis, 2018, 135: 85-93.
[3] HUANG Y, LI B, LIU D J, et al.Fundamental advances in biomass autothermal/oxidative pyrolysis: a review[J]. ACS sustainable chemistry & engineering, 2020, 8(32): 11888-11905.
[4] SUN H L, FENG D D, ZHAO Y J, et al.Characteristics of gas-liquid-solid products in corn straw gasification: effect of the char-tar-H2O interaction[J]. Energy & fuels, 2019, 33(10): 9974-9984.
[5] LI B, ZHAO L J, XIE X, et al.Volatile-char interactions during biomass pyrolysis: effect of char preparation temperature[J]. Energy, 2021, 215: 119189.
[6] 刘雳, 孙川. 我国生物质能企业的融资分析[J]. 全国流通经济, 2020(25): 80-82.
LIU L, SUN C.Analysis of financing of biomass energy enterprises in China[J]. China circulation economy, 2020(25): 80-82.
[7] 孟凡彬, 孟军. 生物质炭化技术研究进展[J]. 生物质化学工程, 2016, 50(6): 61-66.
MENG F B, MENG J.Review of biomass carbonization technology[J]. Biomass chemical engineering, 2016, 50(6): 61-66.
[8] 可存峰, 广萌萌, 张亚宁, 等. 生物质微波热化学转化技术[J]. 东北电力大学学报, 2021, 41(3): 1-9.
KE C F, GUANG M M, ZHANG Y N, et al.Microwaveassisted thermochemical conversion technologies for biomass[J]. Journal of Northeast Electric Power University, 2021, 41(3): 1-9.
[9] 马隆龙, 唐志华, 汪丛伟, 等. 生物质能研究现状及未来发展策略[J]. 中国科学院院刊, 2019, 34(4): 434-442.
MA L L, TANG Z H, WANG C W, et al.Research status and future development strategy of biomass energy[J]. Bulletin of Chinese Academy of Sciences, 2019, 34(4): 434-442.
[10] ZHANG Y, GENG P, LIU R.Synergistic combination of biomass torrefaction and co-gasification: reactivity studies[J]. Bioresource technology, 2017, 245: 225-233.
[11] UMEDA K, NAKAMURA S, LU D, et al.Biomass gasification employing low-temperature carbonization pretreatment for tar reduction[J]. Biomass and bioenergy, 2019, 126: 142-149.
[12] PARK S W, JANG C H, BAEK K R, et al.Torrefaction and low-temperature carbonization of woody biomass: evaluation of fuel characteristics of the products[J]. Energy, 2012, 45(1): 676-685.
[13] 李姗姗. 金属催化生物质热解制备高值化学品的研究[D]. 合肥: 中国科学技术大学, 2021.
LI S S.Study on metal catalyzed biomass pyrolysis for preparation of high-value chemicals[D]. Hefei: University of Science and Technology of China, 2021.
[14] 齐建荟. 磷酸二氢铵对生物质固钾、灰熔融及燃烧特性的影响研究[D]. 济南: 山东大学, 2015.
QI J H.Effect of ammonium dihydrogen phosphate on biomass potassium retention, ash fusibility and combustion characteristics[D]. Ji'nan: Shandong University, 2015.
[15] LI J, LI B, ZHANG X C, et al.The study of flame retardants on thermal degradation and charring process of manchurian ash lignin in the condensed phase[J]. Polymer degradation and stability, 2001, 72(3): 493-498.
[16] PARDO A, ROMERO J, ORTIZ E.High-temperature behaviour of ammonium dihydrogen phosphate[J]. Journal of physics: conference series, 2017, 935: 012050.
[17] QI J H, LI H, HAN K H, et al.Influence of ammonium dihydrogen phosphate on potassium retention and ash melting characteristics during combustion of biomass[J]. Energy, 2016, 102: 244-251.
[18] DEMIRBAŞ A.Calculation of higher heating values of biomass fuels[J]. Fuel, 1997, 76(5): 431-434.
[19] LI K, WANG B, BOLATIBIEKE D, et al.Pyrolysis of biomass impregnated with ammonium dihydrogen phosphate for polygeneration of phenol and supercapacitor electrode material[J]. Frontiers in chemistry, 2020, 8: 436.
[20] 吴贵豪, 朱有健, 樊纪原, 等. 磷酸二氢铵对玉米秆烘焙及固定床燃烧颗粒物排放特性的影响[J]. 化工学报, 2021, 72(6): 3359-3367.
WU G H, ZHU Y J, FAN J Y, et al.Effects of the addition of NH4H2PO4 in corn stalk on torrefaction and PM emissions in fixed bed combustion[J]. CIESC journal, 2021, 72(6): 3359-3367.
[21] DI BLASI C, BRANCA C, GALGANO A.Thermal and catalytic decomposition of wood impregnated with sulfur- and phosphorus-containing ammonium salts[J]. Polymer degradation and stability, 2008, 93(2): 335-346.
[22] 吴玉章, 原田寿郎. 磷酸铵盐处理人工林木材的燃烧性能[J]. 林业科学, 2005, 41(2): 112-116.
WU Y Z, TOSHIRO HARADA.The burning behaviour of plantation wood treated with ammonium phosphate[J]. Scientia silvae sinicae, 2005, 41(2): 112-116.
[23] 范方宇, 邢献军, 蒋汶, 等. 基于能量产率的玉米秸秆成型颗粒炭化工艺优化[J]. 太阳能学报, 2019, 40(1): 172-178.
FAN F Y, XING X J, JIANG W, et al.Optimization of pyrolysis carbonization conditions based on energy yield analysis for corn stover pellets[J]. Acta energiae solaris sinica, 2019, 40(1): 172-178.
[24] 闻蕾, 王景甫, 韩恒超. 烘焙条件对生物质烘焙特性的影响[J]. 新能源进展, 2019, 7(2): 115-122.
WEN L, WANG J F, HAN H C.Effect of torrefaction conditions on the torrefaction characteristics of biomass[J]. Advances in new and renewable energy, 2019, 7(2): 115-122.
[25] 吴玉章. 硼化物及磷酸盐处理人工林木材的燃烧性能比较[J]. 木材工业, 2005, 19(2): 35-38.
WU Y Z.Comparison of burning behavior between boride and ammonium phosphate treated plantation wood[J]. Chinese journal of wood science and technology, 2005, 19(2): 35-38.
[26] 支环, 苏哲安, 黄启忠, 等. 磷酸二氢铵对聚丙烯腈纤维预氧化程度及热稳定性的影响[J]. 炭素技术, 2021, 40(4): 49-55.
ZHI H, SU Z A, HUANG Q Z, et al.Effect of ammonium dihydrogen phosphate on pre-oxidation degree and thermal stability of polyacrylonitrile fiber[J]. Carbon techniques, 2021, 40(4): 49-55.
[27] ABDEL-KADER A, AMMAR A A, SALEH S I.Thermal behaviour of ammonium dihydrogen phosphate crystals in the temperature range 25-600 ℃[J]. Thermochimica acta, 1991, 176: 293-304.
[28] 彭好义, 李志晴, 沈贞, 等. 杨木微波热解产气特性实验研究[J]. 太阳能学报, 2020, 41(4): 235-242.
PENG H Y, LI Z Q, SHEN Z, et al.Experimental study on gas production chareacteristic of polar wood microwave pyrolysis[J]. Acta energiae solaris sinica, 2020, 41(4): 235-242.
[29] CHEN W, CHEN Y Q, YANG H P, et al.Investigation on biomass nitrogen-enriched pyrolysis: influence of temperature[J]. Bioresource technology, 2018, 249: 247-253.
[30] CANCHÉ-ESCAMILLA G, GUIN-AGUILLÓN L, DUARTE-ARANDA S, et al. Characterization of bio-oil and biochar obtained by pyrolysis at high temperatures from the lignocellulosic biomass of the henequen plant[J]. Journal of material cycles and waste management, 2022, 24(2): 751-762.
[31] IRAOLA-ARREGUI I, VAN DER GRYP P, GÖRGENS J F. A review on the demineralisation of pre- and post-pyrolysis biomass and tyre wastes[J]. Waste management, 2018, 79: 667-688.
[32] 李学琴, 吴幼青, 雷廷宙, 等. 生物质焦油热解制富氢燃气的研究进展及展望[J]. 太阳能学报, 2023, 44(7): 530-535.
LI X Q, WU Y Q, LEI T Z, et al.Research progress and prospect of hydrogen-rich gas from biomass tar pyrolysis[J]. Acta energiae solaris sinica, 2023, 44(7): 530-535.
[33] LI S S, LI S Y, WANG C, et al.Catalytic effects of ammonium dihydrogen phosphate on the pyrolysis of lignocellulosic biomass: selective production of furfural and levoglucosenone[J]. Fuel processing technology, 2020, 209: 106525.
[34] 王才威, 张守玉, 姚云隆, 等. 生物质成型炭燃烧特性研究[J]. 太阳能学报, 2019, 40(7): 2014-2020.
WANG C W, ZHANG S Y, YAO Y L, et al.Study on combustion characteristics of carbonized biomass briquettes[J]. Acta energiae solaris sinica, 2019, 40(7): 2014-2020.
[35] ZHAO L, CAO X D, ZHENG W, et al.Copyrolysis of biomass with phosphate fertilizers to improve biochar carbon retention, slow nutrient release, and stabilize heavy metals in soil[J]. ACS sustainable chemistry & engineering, 2016, 4(3): 1630-1636.
PDF(1485 KB)

Accesses

Citation

Detail

Sections
Recommended

/