铁基和硅基材料对有机垃圾厌氧发酵产沼气的促进作用研究

doi:10.19912/j.0254-0096.tynxb.2021-0964

太阳能学报 ›› 2022, Vol. 43 ›› Issue (11): 317-324.DOI: 10.19912/j.0254-0096.tynxb.2021-0964

铁基和硅基材料对有机垃圾厌氧发酵产沼气的促进作用研究

董晓莹^1,2, 付佳辉², 肖永厚², 周扬³, 宁跃文³, 徐卫平^2,4

1.农业农村部农业废弃物能源化利用重点实验室,北京 100021;
2.大连理工大学盘锦产业技术研究院,辽宁省化学助剂合成与分离省市共建重点实验室,盘锦 124221;
3.沈阳工业大学石油化工学院,辽阳 111000;
4.大连理工大学海洋科学与技术学院,盘锦 124221

收稿日期:2021-08-17 出版日期:2022-11-28 发布日期:2023-05-28
通讯作者: 董晓莹（1984—）,女,博士、副研究员,主要从事生物质资源化及气体净化方面的研究。dongxy@dlut.edu.cn
基金资助:
农业农村部规划设计院开放课题（KLERUAR2020-04）; 辽宁省化学助剂合成与分离省市共建重点实验室开放课题（ZJKF2003）

STUDY ON PROMOTING EFFECT OF IRON-BASED AND SILICON-BASED MATERIALS ON BIOGAS PRODUCTION BY ANAEROBICFERMENTATION OF ORGANIC WASTE

Dong Xiaoying^1,2, Fu Jiahui², Xiao Yonghou², Zhou Yang³, Ning Yuewen³, Xu Weiping^2,4

1. Key Laboratory of Energy Resource Utilization, MARA, Beijing 100021, China;
2. Panjin Institute of Industrial Technology, Liaoning Key Laboratory of Chemical Additive Synthesis and Separation, Panjin 124221, China;
3. College of Petroleum and Chemical Engineering, Shenyang University of Technology, Liaoyang 111000, China;
4. School of Marine Science and Technology, Dalian University of Technology, Panjin 124221, China

Received:2021-08-17 Online:2022-11-28 Published:2023-05-28

摘要/Abstract

摘要： 制备并考察3种功能材料（Fe₂O₃、Silicalite-1和Fe₂O₃@Silicalite-1）的3种投加量（50、100和150 mg）对有机垃圾（鸡粪）的厌氧发酵产气影响。结果表明：各功能材料组的日沼气产量和甲烷含量相比于空白组均得到有效提高,其中Fe₂O₃组分别提高31.07%和10.34%;Silicalite-1组分别提高23.98%和12.07%;Fe₂O₃@Silicalite-1组的产气效果最佳,其最高累计产气量和甲烷含量分别提高41.39%和17.24%。由此可见,将纳米Fe₂O₃分散负载在多孔材料（Silicalite-1）上可作为一种有效的厌氧发酵催化剂,该材料可避免传统方法中纳米颗粒的团聚造成的自身性能失活,从而通过厌氧发酵技术耦合复合材料实现有机垃圾处理工艺的能源效益和环境效益。

关键词: Fe₂O₃, Silicalite-1, 有机废物氧化, 厌氧发酵, 沼气, 甲烷

Abstract: Three synthesized functional materials, such as Fe₂O₃, Silicalite-1 and Fe₂O₃@Silicalite-1 are investigated for subsequent promotional effects upon gas generation by utilizing organic waste （chicken manure） in anaerobic fermentation for the first time. The results exhibited that the daily biogas yield and methane contents are effectively improved by using functional materials compared with the blank groups. Among them, the Fe₂O₃@Silicalite-1 demonstrated the best performance in terms of the maximum cumulative gas yield and methane contents are increased by 41.39% and 17.24% compared to date of blank group, respectively. Fe₂O₃ group increases by 31.07% and 10.34%, and Silicalite-1 increases by 23.98% and 12.07% when compared with the date of blank group, respectively. As opposed to agglomeration of nanoparticles in traditional methods, nanostructured Fe₂O₃ dispersed on the surface of porous material Silicate-1 could be employed as an effective anaerobic fermentation catalyst against deactivation caused by agglomeration and hence maintains superior performance. Therefore, the energy and environmental benefits of organic waste treatment process could be accomplished by smart tailoring of composite materials with anaerobic fermentation technology.

Key words: Fe₂O₃, Silicalite-1, organic waste oxygenation, anaerobic fermentation, biogas, methane

中图分类号:

TK513.5

董晓莹, 付佳辉, 肖永厚, 周扬, 宁跃文, 徐卫平. 铁基和硅基材料对有机垃圾厌氧发酵产沼气的促进作用研究[J]. 太阳能学报, 2022, 43(11): 317-324.

Dong Xiaoying, Fu Jiahui, Xiao Yonghou, Zhou Yang, Ning Yuewen, Xu Weiping. STUDY ON PROMOTING EFFECT OF IRON-BASED AND SILICON-BASED MATERIALS ON BIOGAS PRODUCTION BY ANAEROBICFERMENTATION OF ORGANIC WASTE[J]. Acta Energiae Solaris Sinica, 2022, 43(11): 317-324.

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铁基和硅基材料对有机垃圾厌氧发酵产沼气的促进作用研究

STUDY ON PROMOTING EFFECT OF IRON-BASED AND SILICON-BASED MATERIALS ON BIOGAS PRODUCTION BY ANAEROBICFERMENTATION OF ORGANIC WASTE

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