基于生物柴油重整的燃料电池发电系统性能研究

刘洋; 谢俊恩; 陈志超; 修心岩; 于淏名; 秦江

doi:10.19912/j.0254-0096.tynxb.2024-1685

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太阳能学报 ›› 2026, Vol. 47 ›› Issue (2) : 626-632. DOI: 10.19912/j.0254-0096.tynxb.2024-1685

基于生物柴油重整的燃料电池发电系统性能研究

刘洋¹, 谢俊恩¹, 陈志超¹, 修心岩¹, 于淏名¹, 秦江^1,2

作者信息 +

PERFORMANCE STUDY OF FUEL CELL POWER GENERATION SYSTEM BASED ON BIODIESEL REFORMING

Liu Yang¹, Xie Jun’en¹, Chen Zhichao¹, Xiu Xinyan¹, Yu Haoming¹, Qin Jiang^1,2

Author information +

文章历史 +

摘要

提出一种基于生物柴油重整的燃料电池发电系统,通过建模仿真计算,研究水碳比、蒸汽重整温度、燃料电池燃料利用率等参数对系统性能的影响,并基于优化算法得到系统最佳工作点。结果表明：降低水碳比会同时提高重整气内H₂和CO浓度;提高燃料电池燃料利用率能够有效提高系统效率,但过高燃料利用率会产生用于进料预热的额外功率损耗;发电系统额定功率下的最大工作效率为42.21%,在耗油率和碳排放量方面相较柴油发动机均有较大改善。

Abstract

The paper proposes a fuel cell power generation system based on biodiesel reforming. The effects of parameters such as water-carbon ratio, steam reforming temperature, and fuel cell fuel utilization rate on the system performance are investigated through modelling and simulation calculations. Afterwards, the optimal working point of the system is obtained based on an optimization algorithm. The results show that： lowering the steam-carbon ratio increases both H₂ and CO concentrations in the reformed gas; increasing the fuel utilization rate of the fuel cell effectively improves the system efficiency, but excessively high a fuel utilization rate results in additional power loss for feed preheating; the maximum efficiency of the power generation system at rated power is 42.21%, and the power generation system has improved in terms of fuel consumption and carbon emission compared with the diesel engine.

导出引用

刘洋, 谢俊恩, 陈志超, 修心岩, 于淏名, 秦江. 基于生物柴油重整的燃料电池发电系统性能研究[J]. 太阳能学报. 2026, 47(2): 626-632 https://doi.org/10.19912/j.0254-0096.tynxb.2024-1685

Liu Yang, Xie Jun’en, Chen Zhichao, Xiu Xinyan, Yu Haoming, Qin Jiang. PERFORMANCE STUDY OF FUEL CELL POWER GENERATION SYSTEM BASED ON BIODIESEL REFORMING[J]. Acta Energiae Solaris Sinica. 2026, 47(2): 626-632 https://doi.org/10.19912/j.0254-0096.tynxb.2024-1685

中图分类号： TK91

参考文献

[1] 曹湘洪. 氢能开发与利用中的关键问题[J]. 石油炼制与化工, 2017, 48(9): 1-6.
CAO X H.Key to development and application of hydrogen energy[J]. Petroleum processing and petrochemicals, 2017, 48(9): 1-6.
[2] 朱秀珠, 纪亚琨, 孙明汉. 全球燃料电池创新态势演变: 基于“国家-企业-专利”多模网络视角[J]. 太阳能学报, 2023, 44(12): 471-480.
ZHU X Z, JI Y K, SUN M H.Evolution of global fuel cells innovation landscape based on “country-enterprise-patent”multi-mode network perspective[J]. Acta energiae solaris sinica, 2023, 44(12): 471-480.
[3] 袁斌, 潘建欣, 王傲, 等. 燃料电池用柴油重整制氢技术现状与展望[J]. 化工进展, 2020, 39(S1): 107-115.
YUAN B, PAN J X, WANG A, et al.Research progress and perspective of diesel reforming to hydrogen production for fuel cell applications[J]. Chemical industry and engineering progress, 2020, 39(S1): 107-115.
[4] 肖周荣, 李国柱, 王涖, 等. 液体碳氢燃料蒸汽重整制氢催化剂研究进展[J]. 化工进展, 2022, 41(S1): 97-107.
XIAO Z R, LI G Z, WANG L, et al.Research progress of the catalysts for hydrogen production via liquid hydrocarbon fuels steam reforming[J]. Chemical industry and engineering progress, 2022, 41(S1): 97-107.
[5] MA F R, HANNA M A.Biodiesel production: a review[J]. Bioresource technology, 1999, 70(1): 1-15.
[6] 尧命发, 庞阔, 谷静波, 等. 正丁醇/生物柴油高预混压燃燃烧及排放特性的试验[J]. 内燃机学报, 2013, 31(3): 193-199.
YAO M F, PANG K, GU J B, et al.Experiment on combustion and emission characteristics of n-butanol/biodiesel dual fuel HPCC[J]. Transactions of CSICE, 2013, 31(3): 193-199.
[7] 陈冠益, 夏晒歌, 李婉晴, 等. 面向碳中和的生物柴油制备及应用研究进展[J]. 太阳能学报, 2022, 43(9): 343-353.
CHEN G Y, XIA S G, LI W Q, et al.Research progress in preparation and application of biodiesel for carbon neutralty[J]. Acta energiae solaris sinica, 2022, 43(9): 343-353.
[8] MARTIN S, WÖRNER A. On-board reforming of biodiesel and bioethanol for high temperature PEM fuel cells: comparison of autothermal reforming and steam reforming[J]. Journal of power sources, 2011, 196(6): 3163-3171.
[9] NAHAR G A.Hydrogen rich gas production by the autothermal reforming of biodiesel(FAME) for utilization in the solid-oxide fuel cells: a thermodynamic analysis[J]. International journal of hydrogen energy, 2010, 35(17): 8891-8911.
[10] WU H W, LIN K W.Thermodynamic analysis of hydrogenrich syngas production with a mixture of aqueous urea and biodiesel[J]. International journal of hydrogen energy, 2018, 43(14): 6804-6814.
[11] LIAO C H, CHEIN R.Thermodynamic analysis of syngas production from biodiesel via chemical looping reforming[J]. International journal of hydrogen energy, 2021, 46(31): 16591-16602.
[12] AUTHAYANUN S, MAMLOUK M, ARPORNWICHANOP A.Maximizing the efficiency of a HT-PEMFC system integrated with glycerol reformer[J]. International journal of hydrogen energy, 2012, 37(8): 6808-6817.
[13] SCOTT K, MAMLOUK M.A cell voltage equation for an intermediate temperature proton exchange membrane fuel cell[J]. International journal of hydrogen energy, 2009, 34(22): 9195-9202.
[14] WU W, ZHAI C, SUI Y R, et al.A novel distributed energy system using high-temperature proton exchange membrane fuel cell integrated with hybrid-energy heat pump[J]. Energy conversion and management, 2021, 235: 113990.
[15] KIM J, KIM M, KANG T, et al.Degradation modeling and operational optimization for improving the lifetime of high-temperature PEM(proton exchange membrane) fuel cells[J]. Energy, 2014, 66: 41-49.
[16] GUO X R, ZHANG H C.Performance analyses of a combined system consisting of high-temperature polymer electrolyte membrane fuel cells and thermally regenerative electrochemical cycles[J]. Energy, 2020, 193: 116720.
[17] 陈家城, 周苏. 大功率质子交换膜燃料电池建模及仿真[J]. 太阳能学报, 2024, 45(3): 290-297.
CHEN J C, ZHOU S.Modeling and simulation of high-power proton exchange membrane fuel cells[J]. Acta energiae solaris sinica, 2024, 45(3): 290-297.
[18] GUO X R, ZHANG H C, GUO Y M, et al.A novel triple-cycle system based on high-temperature proton exchange membrane fuel cell, thermoelectric generator, and thermally regenerative electrochemical refrigerator for power and cooling cogeneration[J]. International journal of energy research, 2022, 46(6): 7529-7541.
[19] COLLINS-MARTINEZ V, ESCOBEDO BRETADO M, MELÉNDEZ ZARAGOZA M, et al. Absorption enhanced reforming of light alcohols (methanol and ethanol) for the production of hydrogen: thermodynamic modeling[J]. International journal of hydrogen energy, 2013, 38(28): 12539-12553.
[20] 刘禾, 秦江, 郭发福, 等. 基于吸附强化重整制氢的燃料电池-涡轮混合发电系统性能研究[J]. 工程热物理学报, 2022, 43(9): 2340-2346.
LIU H, QIN J, GUO F F, et al.Study on the performance of fuel cell-gas turbine hybrid power generation system based on the absorption enhanced reforming for hydrogen production[J]. Journal of engineering thermophysics, 2022, 43(9): 2340-2346.
[21] 李成杰, 王紫璇, 哈婵, 等. 基于甲醇燃料的航空燃料电池内燃机混合动力系统性能分析[J]. 推进技术, 2024, 45(3): 122-130.
LI C J, WANG Z X, HA C, et al.Performance analysis of hybrid power system of aviation fuel cell internal combustion engine with methanol fuel[J]. Journal of propulsion technology, 2024, 45(3): 122-130.