直接电加热的SiC泡沫乙醇水蒸气催化重整制氢的数值模拟

宋旭, 鲍泽威, 宗文刚

太阳能学报 ›› 2026, Vol. 47 ›› Issue (2) : 768-775.

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太阳能学报 ›› 2026, Vol. 47 ›› Issue (2) : 768-775. DOI: 10.19912/j.0254-0096.tynxb.2024-1842

直接电加热的SiC泡沫乙醇水蒸气催化重整制氢的数值模拟

  • 宋旭, 鲍泽威, 宗文刚
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NUMERICAL SIMULATION OF HYDROGEN PRODUCTION BY CATALYTIC REFORMING OF ETHANOL WATER STEAM FROM SiC FOAM WITH DIRECT ELECTRICAL HEATING

  • Song Xu, Bao Zewei, Zong Wen’gang
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摘要

利用数值模拟方法建立一种直接电加热SiC泡沫催化剂载体的乙醇水蒸气重整制氢反应器模型。基于所建立的数学模型对重整反应器性能进行研究。重点分析入口温度、水醇比、入口流速和电加热功率等因素的影响。以乙醇转化率和反应物的组分浓度作为评价指标。研究结果表明,升高入口温度和电加热功率能为重整反应提供更多热量,从而提高反应温度,促进重整反应进行。当入口温度从873.15 K提高至1073.15 K时,乙醇转化率从95.5%显著提高至98.2%;当电流功率从14 W增至24 W时,乙醇转化率由94.6%升至98.9%。此外,增大水醇比和减小入口流速也可有效提高乙醇转化率。

Abstract

This study employs numerical simulations to develop a model for an ethanol steam reforming reactor aimed at hydrogen production, featuring the direct electrical heating of a SiC foam catalyst carrier. The model investigates reactor performance under varying operating conditions, including inlet temperature, water-to-ethanol ratio, inlet flow rate, and electrical heating power, with ethanol conversionrate and reactant composition used as evaluation metrics. The results reveal that increasing inlet temperature and electrical heating power effectively raises the reaction temperature, thereby accelerating the reforming reaction. Specifically, ethanol conversionrate increases significantly from 95.5% to 98.2%, as the inlet temperature rises from 873.15 K to 1073.15 K. Similarly, boosting electrical heating power from 14 W to 24 W improves ethanol conversionrate from 94.6% to 98.9%. Furthermore, optimizing the water-to-ethanol ratio and reducing the inlet flow rate are also effective strategies for further enhancing ethanol conversion.

关键词

乙醇 / 蒸汽重整 / 数值模型 / 结构催化剂 / SiC泡沫 / 焦耳效应

Key words

ethanol / steam reforming / numerical model / structured catalyst / SiC foam / joule effect

引用本文

导出引用
宋旭, 鲍泽威, 宗文刚. 直接电加热的SiC泡沫乙醇水蒸气催化重整制氢的数值模拟[J]. 太阳能学报. 2026, 47(2): 768-775 https://doi.org/10.19912/j.0254-0096.tynxb.2024-1842
Song Xu, Bao Zewei, Zong Wen’gang. NUMERICAL SIMULATION OF HYDROGEN PRODUCTION BY CATALYTIC REFORMING OF ETHANOL WATER STEAM FROM SiC FOAM WITH DIRECT ELECTRICAL HEATING[J]. Acta Energiae Solaris Sinica. 2026, 47(2): 768-775 https://doi.org/10.19912/j.0254-0096.tynxb.2024-1842
中图分类号: TK91   

参考文献

[1] 张盛, 郑津洋, 戴剑锋, 等. 可再生能源大规模制氢及储氢系统研究进展[J]. 太阳能学报, 2024, 45(1): 457-465.
ZHANG S, ZHENG J Y, DAI J F, et al.Research progress on renewable energy system coupled with large-scale hydrogen production and storage[J]. Acta energiae solaris sinica, 2024, 45(1): 457-465.
[2] 屈柏林, 张雪霞, 陈维荣, 等计及微网余电制氢的加氢站设备容量优化配置[J]. 太阳能学报, 2024, 45(10): 11-21.
QU B L, ZHANG X X, CHEN W R, et al.Capacity optimization configuration of equipment in hydrogen refueling station considering microgrid residual electricity to hydrogen production[J]. Acta energiae solaris sinica, 2024, 45(10): 11-21.
[3] ROSSETTI I, TRIPODI A, RAMIS G.Hydrogen, ethylene and power production from bioethanol: ready for the renewable market?[J]. International journal of hydrogen energy, 2020, 45(17): 10292-10303.
[4] GUO S X, LIU S B, LIU G Z.Modulation of Rh species in Rh/Al2O3/FeCrAl-foam structured catalysts for steam reforming of toluene[J]. Chemical engineering journal, 2024, 480: 148237.
[5] 李攀, 马腾杰, 林钰程, 等. 生物质热化学转化制氢技术研究进展[J]. 太阳能学报, 2024, 45(10): 645-654.
LI P, MA T J, LIN Y C, et al.Advancements in hydrogen production from biomass thermochemical conversion[J]. Acta energiae solaris sinica, 2024, 45(10): 645-654.
[6] 李恺, 刘锦轩, 王志崇, 等. 泡沫SiC基结构化催化剂的制备及其在多相催化中的应用进展[J]. 中国陶瓷, 2025, 61(2): 1-10.
LI K, LIU J X, WANG Z C, et al.Preparation of foam SiC-based structured catalysts and its application progress in heterogeneous catalysis[J]. China ceramics, 2025, 61(2): 1-10.
[7] 雷宇, 袁熹, 王颖, 等. 基于太阳能的甲烷重整制氢技术研究进展[J]. 太阳能学报, 2022, 43(12): 154-160.
LEI Y, YUAN X, WANG Y, et al.Research progress of hydrogen production from methane reforming based on solar energy[J]. Acta energiae solaris sinica, 2022, 43(12): 154-160.
[8] LIN Y X, YANG C, ZHANG W, et al.Lattice Boltzmann study on the effect of hierarchical pore structure on fluid flow and coke formation characteristics in open-cell foam for dry reforming of methane[J]. Chemical engineering science, 2023, 268: 118380.
[9] 王治斌, 孙来芝, 陈雷, 等. Ni、Fe负载CaO催化剂作用下生物油模化物水蒸气催化重整制氢研究[J]. 太阳能学报, 2022, 43(2): 16-21.
WANG Z B, SUN L Z, CHEN L, et al.Steam catalytic reforming of simulated bio-oil compounds with Ni and Fe supported by CaO catalyst for hydrogen production[J]. Acta energiae solaris sinica, 2022, 43(2): 16-21.
[10] WANG Y C, LIU H Y, MEI D Q, et al.A novel thermally autonomous methanol steam reforming microreactor using SiC honeycomb ceramic as catalyst support for hydrogen production[J]. International journal of hydrogen energy, 2021, 46(51): 25878-25892.
[11] ZHENG L, AMBROSETTI M, ZAIO F, et al.Direct electrification of Rh/Al2O3 washcoated SiSiC foams for methane steam reforming: an experimental and modelling study[J]. International journal of hydrogen energy, 2023, 48(39): 14681-14696.
[12] ZHENG L, AMBROSETTI M, MARANGONI D, et al.Electrified methane steam reforming on a washcoated SiSiC foam for low-carbon hydrogen production[J]. AIChE journal, 2023, 69(1): e17620.
[13] GHOUSE J H, ADAMS T A.A multi-scale dynamic two-dimensional heterogeneous model for catalytic steam methane reforming reactors[J]. International journal of hydrogen energy, 2013, 38(24): 9984-9999.
[14] DE-SOUZA M, ZANIN G M, MORAES F F.Parametric study of hydrogen production from ethanol steam reforming in a membrane microreactor[J]. Brazilian journal of chemical engineering, 2013, 30(2): 355-367.
[15] XU J G, FROMENT G F.Methane steam reforming, methanation and water-gas shift: I. intrinsic kinetics[J]. AIChE journal, 1989, 35(1): 88-96.
[16] PATEL M, JINDAL T K, PANT K K.Kinetic study of steam reforming of ethanol on Ni-based ceria-zirconia catalyst[J]. Industrial & engineering chemistry research, 2013, 52(45): 15763-15771.
[17] GUO W M, HU T C, QIN H, et al.Preparation and in situ reduction of Ni/SiCxOy catalysts supported on porous SiC ceramic for ethanol steam reforming[J]. Ceramics international, 2021, 47(10): 13738-13744.
[18] 郭恒涛, 王学涛, 邢利利, 等. 生物质水蒸气催化重整制氢研究进展[J]. 生物质化学工程, 2023, 57(4): 60-70.
GUO H T, WANG X T, XING L L, et al.Research advance in biomass steam catalytic reforming for hydrogen production[J]. Biomass chemical engineering, 2023, 57(4): 60-70.
[19] BENITO M, SANZ J L, ISABEL R, et al.Bio-ethanol steam reforming: insights on the mechanism for hydrogen production[J]. Journal of power sources, 2005, 151: 11-17.
[20] 朱小明, 闫常峰, 郭常青, 等. 催化剂Ni-Cu/SrCeO3在乙醇水蒸气重整制氢的催化研究[J]. 太阳能学报, 2012, 33(5): 878-881.
ZHU X M, YAN C F, GUO C Q, et al.Hydrogen production reserach by steam reforming of ethanol over Ni-Cu/SrCeO3 catalyst[J]. Acta energiae solaris sinica, 2012, 33(5): 878-881.
[21] ZHANG J L, HU S, DING Y, et al.Nickel based catalyst supported by carbon aerogel prepared from waste pomelo peel to crack ethanol for hydrogen production: catalytic performance and mechanism[J]. Fuel, 2023, 346: 128278.
[22] COMPAGNONI M, TRIPODI A, ROSSETTI I.Parametric study and kinetic testing for ethanol steam reforming[J]. Applied catalysis B: environmental, 2017, 203: 899-909.
[23] MENDES D, MENDES A, MADEIRA L M, et al.The water-gas shift reaction: from conventional catalytic systems to Pd-based membrane reactors: a review[J]. Asia-Pacific journal of chemical engineering, 2010, 5(1): 111-137.
[24] SIDHU T P K, GOVIL A, ROY S. Optimal monolithic configuration for heat integrated ethanol steam reformer[J]. International journal of hydrogen energy, 2017, 42(12): 7770-7785.

基金

四川省自然科学基金面上项目(2024NSFSC0280)

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