不同PbBr2浓度对CsPbBr3钙钛矿太阳电池性能的影响

崔天洋, 杨雯, 杨培志

太阳能学报 ›› 2026, Vol. 47 ›› Issue (5) : 613-619.

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太阳能学报 ›› 2026, Vol. 47 ›› Issue (5) : 613-619. DOI: 10.19912/j.0254-0096.tynxb.2024-2311

不同PbBr2浓度对CsPbBr3钙钛矿太阳电池性能的影响

  • 崔天洋, 杨雯, 杨培志
作者信息 +

EFFECT OF DIFFERENT PbBr2 CONCENTRATIONS ON PERFORMANCE OF CsPbBr3 PEROVSKITE SOLAR CELLS

  • Cui Tianyang, Yang Wen, Yang Peizhi
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摘要

该文通过多步旋涂法制备基于不同PbBr2浓度的CsPbBr3太阳电池。研究不同PbBr2浓度对CsPbBr3太阳电池光伏性能的影响。结果表明,相比于0.6、0.8和1.2 mol/L PbBr2浓度的CsPbBr3太阳电池,1.0 mol/L PbBr2浓度的CsPbBr3太阳电池的短路电流密度得到有效提高,达7.47 mA/cm2,进而使器件效率提升至7.30%。经测试表征发现,基于1.0 mol/L PbBr2浓度制备的CsPbBr3吸收层具有更好的均匀性、更低的粗糙度、更高的光吸收率以及更强的电子和空穴分离能力,从而提升器件效率。

Abstract

In this work, the CsPbBr3 solar cells based on different concentrations of PbBr2 are prepared by a multi-step spin coating method. The effect of different PbBr2 concentrations on the photovoltaic performance of CsPbBr3 solar cells is studied. The results showed that compared with CsPbBr3 solar cells based on 0.6, 0.8 and 1.2 mol/L PbBr2, the short-circuit current density of CsPbBr3 solar cell with 1.0 mol/L PbBr2 is effectively improved (7.47 mA/cm2), which leads to an improvement in device efficiency (7.30%). Characterization tests revealed that the CsPbBr₃ absorber layer prepared with a PbBr2 concentration of 1.0 mol/L exhibits better uniformity, lower roughness, higher light absorption, and stronger electron-hole separation capability, leading to improved device efficiency.

关键词

钙钛矿太阳电池 / 太阳电池效率 / 薄膜制备 / 前驱体 / CsPbBr3

Key words

perovskite solar cells / solar cell efficiency / film preparation / precursor / CsPbBr3

引用本文

导出引用
崔天洋, 杨雯, 杨培志. 不同PbBr2浓度对CsPbBr3钙钛矿太阳电池性能的影响[J]. 太阳能学报. 2026, 47(5): 613-619 https://doi.org/10.19912/j.0254-0096.tynxb.2024-2311
Cui Tianyang, Yang Wen, Yang Peizhi. EFFECT OF DIFFERENT PbBr2 CONCENTRATIONS ON PERFORMANCE OF CsPbBr3 PEROVSKITE SOLAR CELLS[J]. Acta Energiae Solaris Sinica. 2026, 47(5): 613-619 https://doi.org/10.19912/j.0254-0096.tynxb.2024-2311
中图分类号: TM914.4   

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基金

云南省西南联合研究生院科技专项(202302A0370009); 云南省基础研究重点基金(202201AS070023); “兴滇英才支持计划”,“春城计划”高层次人才引进培养工程(2022SCP005); 建设面向南亚东南亚科技创新中心专项(202403AP140015)

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